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学科主题: 物理化学
题名: One-pot catalytic conversion of cellulose to ethylene glycol and other chemicals: From fundamental discovery to potential commercialization
作者: Zheng, Mingyuan1;  Pang, Jifeng1;  Wang, Aiqin1;  Zhang, Tao1
通讯作者: 张涛
关键词: Biomass ;  Cellulose ;  Ethylene glycol ;  Tungstenic catalyst ;  Hydrogenation
刊名: CHINESE JOURNAL OF CATALYSIS
发表日期: 2014-05-01
DOI: 10.1016/S1872-2067(14)60013-9
卷: 35, 期:5, 页:602-613
收录类别: SCI ;  ISTP
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences ;  Technology
类目[WOS]: Chemistry, Applied ;  Chemistry, Physical ;  Engineering, Chemical
研究领域[WOS]: Chemistry ;  Engineering
英文摘要: The one-pot catalytic conversion of cellulose to ethylene glycol (CEG) is a highly attractive way for biomass utilization to lessen the consumption of fossil energy resources. In this paper, we reviewed the disclosure of the CEG process and the rapid progress in the development of highly efficient and robust catalysts for it. Based on our study of tungstenic catalysts, we discuss the reaction mechanism, in which the reaction routes, catalyst states, and catalytic roles of the tungsten species and hydrogenation sites in the cascade reactions are understood clearly. With future applications in mind, the conversion of raw cellulosic biomass and the strategy to develop an efficient CEG process for commercialization are discussed, and a model where the CEG process is incorporated into a bio-refinery process of acetone-n-butanol-ethanol (ABE) production is presented. (C) 2014, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.
关键词[WOS]: TUNGSTEN CARBIDE CATALYSTS ;  HYDRAZINE DECOMPOSITION ;  LIGNOCELLULOSIC BIOMASS ;  SELECTIVE CONVERSION ;  BIMETALLIC CATALYSTS ;  RANEY NI ;  MICROCRYSTALLINE CELLULOSE ;  1,2-PROPYLENE GLYCOL ;  GAMMA-VALEROLACTONE ;  RUTHENIUM CATALYST
语种: 英语
WOS记录号: WOS:000335622300002
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/144217
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China

Recommended Citation:
Zheng, Mingyuan,Pang, Jifeng,Wang, Aiqin,et al. One-pot catalytic conversion of cellulose to ethylene glycol and other chemicals: From fundamental discovery to potential commercialization[J]. CHINESE JOURNAL OF CATALYSIS,2014,35(5):602-613.
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