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学科主题: 物理化学
题名: Chiral Phosphoric Acid-Catalyzed Asymmetric Transfer Hydrogenation of Quinolin-3-amines
作者: Cai, Xian-Feng1, 2;  Guo, Ran-Ning2;  Feng, Guang-Shou2;  Wu, Bo2;  Zhou, Yong-Gui2
通讯作者: 周永贵
刊名: ORGANIC LETTERS
发表日期: 2014-05-16
DOI: 10.1021/ol500954j
卷: 16, 期:10, 页:2680-2683
收录类别: SCI ;  IC ;  CCR
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: A chiral phosphoric acid catalyzed asymmetric transfer hydrogenation of aromatic amines, quinolin-3-amines, was successfully developed with up to 99% ee. To supplement our previous work on the Ir-catalyzed asymmetric hydrogenation of 2-alkyl substituted quinolin-3-amines, a number of 2-aryl substituted substrates were reduced to provide a series of valuable chiral exocyclic amines with high diastereo- and enantioselectivities.
关键词[WOS]: ENANTIOSELECTIVE TRANSFER HYDROGENATION ;  ALPHA-IMINO ESTERS ;  ORGANOCATALYTIC TRANSFER HYDROGENATION ;  BRONSTED ACID ;  REDUCTIVE AMINATION ;  HANTZSCH ESTERS ;  HETEROAROMATIC-COMPOUNDS ;  2,9-SUBSTITUTED 1,10-PHENANTHROLINES ;  ISOQUINOLINIUM SALTS ;  RELAY CATALYSIS
语种: 英语
WOS记录号: WOS:000336199200028
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/144239
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Dalian Univ Technol, Dept Chem, Dalian 116012, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China

Recommended Citation:
Cai, Xian-Feng,Guo, Ran-Ning,Feng, Guang-Shou,et al. Chiral Phosphoric Acid-Catalyzed Asymmetric Transfer Hydrogenation of Quinolin-3-amines[J]. ORGANIC LETTERS,2014,16(10):2680-2683.
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