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学科主题: 物理化学
题名: Synthesis of Diesel or Jet Fuel Range Cycloalkanes with 2-Methylfuran and Cyclopentanone from Lignocellulose
作者: Li, Guangyi1, 2;  Li, Ning1;  Wang, Xinkui3;  Sheng, Xueru1, 2;  Li, Shanshan1, 2;  Wang, Aiqin1;  Cong, Yu1;  Wang, Xiaodong1;  Zhang, Tao1
通讯作者: 李宁 ;  张涛
刊名: ENERGY & FUELS
发表日期: 2014-08-01
DOI: 10.1021/ef500676z
卷: 28, 期:8, 页:5112-5118
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Technology
类目[WOS]: Energy & Fuels ;  Engineering, Chemical
研究领域[WOS]: Energy & Fuels ;  Engineering
英文摘要: 2-Methylfuran (2-MF) and cyclopentanone (CPO) are the selective hydrogenation products of furfural, which can be produced in industrial scale with lignocellulose. In this work, renewable diesel or jet fuel range branched alkanes and cycloalkanes were first synthesized simultaneously by the solvent-free hydroxyalkylation/alkylation (HAA) of 2-MF and CPO followed by hydrodeoxygenation (HDO). Among the solid acid catalysts used in this work, Nafion-212 resin exhibited the best activity and selectivity for the HAA of 2-MF and CPO. The excellent performance of Nafion-212 resin can be attributed to the high acid strength of this catalyst. After the HDO of the HAA products of 2-MF and CPO over several nickel catalysts, a mixture of jet fuel range branched alkanes and cycloalkanes with relatively higher density was obtained at high carbon yield. Compared with Ni/SiO2, acidic support loaded nickel catalysts are more active in the HDO process, which may be attributed to the promotion effect of acid sites in dehydration and the ring opening reaction of furan compounds.
关键词[WOS]: HIGH-QUALITY DIESEL ;  TOLERANT SOLID ACID ;  CATALYTIC CONVERSION ;  RENEWABLE DIESEL ;  TRANSPORTATION FUELS ;  ZIRCONIUM-PHOSPHATE ;  LIQUID ALKANES ;  BIOMASS ;  HEMICELLULOSE ;  CELLULOSE
语种: 英语
WOS记录号: WOS:000340808800031
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/144251
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Grad Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.Dalian Univ Technol, Sch Chem Engn, Lab Adv Mat & Catalyt Engn, Dalian 116024, Peoples R China

Recommended Citation:
Li, Guangyi,Li, Ning,Wang, Xinkui,et al. Synthesis of Diesel or Jet Fuel Range Cycloalkanes with 2-Methylfuran and Cyclopentanone from Lignocellulose[J]. ENERGY & FUELS,2014,28(8):5112-5118.
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