DICP OpenIR
Subject Area物理化学
Synthesis of Diesel or Jet Fuel Range Cycloalkanes with 2-Methylfuran and Cyclopentanone from Lignocellulose
Li, Guangyi1,2; Li, Ning1; Wang, Xinkui3; Sheng, Xueru1,2; Li, Shanshan1,2; Wang, Aiqin1; Cong, Yu1; Wang, Xiaodong1; Zhang, Tao1; Li N(李宁); Zhang T(张涛)
Source PublicationENERGY & FUELS
2014-08-01
DOI10.1021/ef500676z
Volume28Issue:8Pages:5112-5118
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Technology
WOS SubjectEnergy & Fuels ; Engineering, Chemical
WOS Research AreaEnergy & Fuels ; Engineering
WOS KeywordHIGH-QUALITY DIESEL ; TOLERANT SOLID ACID ; CATALYTIC CONVERSION ; RENEWABLE DIESEL ; TRANSPORTATION FUELS ; ZIRCONIUM-PHOSPHATE ; LIQUID ALKANES ; BIOMASS ; HEMICELLULOSE ; CELLULOSE
Abstract2-Methylfuran (2-MF) and cyclopentanone (CPO) are the selective hydrogenation products of furfural, which can be produced in industrial scale with lignocellulose. In this work, renewable diesel or jet fuel range branched alkanes and cycloalkanes were first synthesized simultaneously by the solvent-free hydroxyalkylation/alkylation (HAA) of 2-MF and CPO followed by hydrodeoxygenation (HDO). Among the solid acid catalysts used in this work, Nafion-212 resin exhibited the best activity and selectivity for the HAA of 2-MF and CPO. The excellent performance of Nafion-212 resin can be attributed to the high acid strength of this catalyst. After the HDO of the HAA products of 2-MF and CPO over several nickel catalysts, a mixture of jet fuel range branched alkanes and cycloalkanes with relatively higher density was obtained at high carbon yield. Compared with Ni/SiO2, acidic support loaded nickel catalysts are more active in the HDO process, which may be attributed to the promotion effect of acid sites in dehydration and the ring opening reaction of furan compounds.
Language英语
WOS IDWOS:000340808800031
Citation statistics
Cited Times:48[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/144251
Collection中国科学院大连化学物理研究所
Corresponding AuthorLi N(李宁); Zhang T(张涛)
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Grad Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.Dalian Univ Technol, Sch Chem Engn, Lab Adv Mat & Catalyt Engn, Dalian 116024, Peoples R China
Recommended Citation
GB/T 7714
Li, Guangyi,Li, Ning,Wang, Xinkui,et al. Synthesis of Diesel or Jet Fuel Range Cycloalkanes with 2-Methylfuran and Cyclopentanone from Lignocellulose[J]. ENERGY & FUELS,2014,28(8):5112-5118.
APA Li, Guangyi.,Li, Ning.,Wang, Xinkui.,Sheng, Xueru.,Li, Shanshan.,...&张涛.(2014).Synthesis of Diesel or Jet Fuel Range Cycloalkanes with 2-Methylfuran and Cyclopentanone from Lignocellulose.ENERGY & FUELS,28(8),5112-5118.
MLA Li, Guangyi,et al."Synthesis of Diesel or Jet Fuel Range Cycloalkanes with 2-Methylfuran and Cyclopentanone from Lignocellulose".ENERGY & FUELS 28.8(2014):5112-5118.
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