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学科主题物理化学
Synthesis of Diesel or Jet Fuel Range Cycloalkanes with 2-Methylfuran and Cyclopentanone from Lignocellulose
Li, Guangyi1,2; Li, Ning1; Wang, Xinkui3; Sheng, Xueru1,2; Li, Shanshan1,2; Wang, Aiqin1; Cong, Yu1; Wang, Xiaodong1; Zhang, Tao1; Li N(李宁); Zhang T(张涛)
刊名ENERGY & FUELS
2014-08-01
DOI10.1021/ef500676z
28期:8页:5112-5118
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Technology
类目[WOS]Energy & Fuels ; Engineering, Chemical
研究领域[WOS]Energy & Fuels ; Engineering
关键词[WOS]HIGH-QUALITY DIESEL ; TOLERANT SOLID ACID ; CATALYTIC CONVERSION ; RENEWABLE DIESEL ; TRANSPORTATION FUELS ; ZIRCONIUM-PHOSPHATE ; LIQUID ALKANES ; BIOMASS ; HEMICELLULOSE ; CELLULOSE
英文摘要2-Methylfuran (2-MF) and cyclopentanone (CPO) are the selective hydrogenation products of furfural, which can be produced in industrial scale with lignocellulose. In this work, renewable diesel or jet fuel range branched alkanes and cycloalkanes were first synthesized simultaneously by the solvent-free hydroxyalkylation/alkylation (HAA) of 2-MF and CPO followed by hydrodeoxygenation (HDO). Among the solid acid catalysts used in this work, Nafion-212 resin exhibited the best activity and selectivity for the HAA of 2-MF and CPO. The excellent performance of Nafion-212 resin can be attributed to the high acid strength of this catalyst. After the HDO of the HAA products of 2-MF and CPO over several nickel catalysts, a mixture of jet fuel range branched alkanes and cycloalkanes with relatively higher density was obtained at high carbon yield. Compared with Ni/SiO2, acidic support loaded nickel catalysts are more active in the HDO process, which may be attributed to the promotion effect of acid sites in dehydration and the ring opening reaction of furan compounds.
语种英语
WOS记录号WOS:000340808800031
引用统计
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/144251
专题中国科学院大连化学物理研究所
通讯作者Li N(李宁); Zhang T(张涛)
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Grad Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.Dalian Univ Technol, Sch Chem Engn, Lab Adv Mat & Catalyt Engn, Dalian 116024, Peoples R China
推荐引用方式
GB/T 7714
Li, Guangyi,Li, Ning,Wang, Xinkui,et al. Synthesis of Diesel or Jet Fuel Range Cycloalkanes with 2-Methylfuran and Cyclopentanone from Lignocellulose[J]. ENERGY & FUELS,2014,28(8):5112-5118.
APA Li, Guangyi.,Li, Ning.,Wang, Xinkui.,Sheng, Xueru.,Li, Shanshan.,...&张涛.(2014).Synthesis of Diesel or Jet Fuel Range Cycloalkanes with 2-Methylfuran and Cyclopentanone from Lignocellulose.ENERGY & FUELS,28(8),5112-5118.
MLA Li, Guangyi,et al."Synthesis of Diesel or Jet Fuel Range Cycloalkanes with 2-Methylfuran and Cyclopentanone from Lignocellulose".ENERGY & FUELS 28.8(2014):5112-5118.
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