DICP OpenIR
学科主题物理化学
Rhodium-Catalyzed Cyclization of Diynes with Nitrones: A Formal [2+2+5] Approach to Bridged Eight-Membered Heterocycles
Wang, Chunxiang; Wang, Dongping; Yan, Hao; Wang, Haolong; Pan, Bin; Xin, Xiaoyi; Li, Xincheng; Wu, Fan; Wan, Boshun; Wan BS(万伯顺)
关键词Alkenylation c h Activation Cyclization Nitrones Rhodium
刊名ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
2014-10-27
DOI10.1002/anie.201407394
53期:44页:11940-11943
收录类别SCI ; IC ; CCR
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Multidisciplinary
研究领域[WOS]Chemistry
关键词[WOS]DIASTEREOSELECTIVE 1,3-DIPOLAR CYCLOADDITION ; C-H BONDS ; COMPLEXES ; PALLADIUM ; CYCLOPROPANES ; CARBENE ; KETONES ; 2-(1-ALKYNYL)-2-ALKEN-1-ONES ; PYRIDINES ; REAGENTS
英文摘要N-aryl-substituted nitrones were employed as five-atom coupling partners in the rhodium-catalyzed cyclization with diynes. In this reaction, the nitrone moiety served as a directing group for the catalytic C-H activation of the N-aryl ring. This formal [2+2+5] approach allows rapid access to bridged eight-membered heterocycles with broad substrate scope. The results of this study may provide new insight into the chemistry of nitrones and find applications in the synthesis of other heterocycles.
语种英语
WOS记录号WOS:000344050700042
引用统计
被引频次:29[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/144260
专题中国科学院大连化学物理研究所
通讯作者Wan BS(万伯顺)
作者单位Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
推荐引用方式
GB/T 7714
Wang, Chunxiang,Wang, Dongping,Yan, Hao,et al. Rhodium-Catalyzed Cyclization of Diynes with Nitrones: A Formal [2+2+5] Approach to Bridged Eight-Membered Heterocycles[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2014,53(44):11940-11943.
APA Wang, Chunxiang.,Wang, Dongping.,Yan, Hao.,Wang, Haolong.,Pan, Bin.,...&万伯顺.(2014).Rhodium-Catalyzed Cyclization of Diynes with Nitrones: A Formal [2+2+5] Approach to Bridged Eight-Membered Heterocycles.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,53(44),11940-11943.
MLA Wang, Chunxiang,et al."Rhodium-Catalyzed Cyclization of Diynes with Nitrones: A Formal [2+2+5] Approach to Bridged Eight-Membered Heterocycles".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 53.44(2014):11940-11943.
条目包含的文件
文件名称/大小 文献类型 版本类型 开放类型 使用许可
2014r4x7b1m4cg.PDF(396KB)期刊论文作者接受稿开放获取CC BY-NC-SA请求全文
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[Wang, Chunxiang]的文章
[Wang, Dongping]的文章
[Yan, Hao]的文章
百度学术
百度学术中相似的文章
[Wang, Chunxiang]的文章
[Wang, Dongping]的文章
[Yan, Hao]的文章
必应学术
必应学术中相似的文章
[Wang, Chunxiang]的文章
[Wang, Dongping]的文章
[Yan, Hao]的文章
相关权益政策
暂无数据
收藏/分享
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。