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学科主题: 物理化学
题名: DABCO-Catalyzed Synthesis of Trifluoromethylated Furans from Propargyl Alcohols and Methyl 2-Perfluoroalkynoate
作者: Chong, Qinglei1;  Xin, Xiaoyi1;  Wang, Chunxiang1;  Wu, Fan1;  Wang, Haolong1;  Shi, Ji-cheng2;  Wan, Boshun1
通讯作者: 施继成 ;  万伯顺
刊名: JOURNAL OF ORGANIC CHEMISTRY
发表日期: 2014-03-07
DOI: 10.1021/jo4028424
卷: 79, 期:5, 页:2105-2110
收录类别: SCI ;  IC ;  CCR
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: The DABCO-catalyzed reaction of propargyl alcohols with methyl 2-perfluoroalkynoate to give trifluoromethylated furans in up to 98% yield under mild conditions has been developed. The established allene-enol and control experiments indicate that the reaction should proceed through a Michael addition and Claisen rearrangement/cyclization process.
关键词[WOS]: FUNCTIONALIZED POLYSUBSTITUTED FURANS ;  POT REGIOSPECIFIC SYNTHESIS ;  CLAISEN REARRANGEMENT ;  VINYL ETHERS ;  MEDICINAL CHEMISTRY ;  AROMATIC-COMPOUNDS ;  DOMINO ACCESS ;  ENOL-ETHERS ;  DERIVATIVES ;  FLUORINE
语种: 英语
WOS记录号: WOS:000332756500023
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/144266
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Guangdong Univ Petrochem Technol, Coll Chem Engn, Maoming 525000, Peoples R China

Recommended Citation:
Chong, Qinglei,Xin, Xiaoyi,Wang, Chunxiang,et al. DABCO-Catalyzed Synthesis of Trifluoromethylated Furans from Propargyl Alcohols and Methyl 2-Perfluoroalkynoate[J]. JOURNAL OF ORGANIC CHEMISTRY,2014,79(5):2105-2110.
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