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学科主题物理化学
DABCO-Catalyzed Synthesis of Trifluoromethylated Furans from Propargyl Alcohols and Methyl 2-Perfluoroalkynoate
Chong, Qinglei1; Xin, Xiaoyi1; Wang, Chunxiang1; Wu, Fan1; Wang, Haolong1; Shi, Ji-cheng2; Wan, Boshun1; Shi JC(施继成); Wan BS(万伯顺)
刊名JOURNAL OF ORGANIC CHEMISTRY
2014-03-07
DOI10.1021/jo4028424
79期:5页:2105-2110
收录类别SCI ; IC ; CCR
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Organic
研究领域[WOS]Chemistry
关键词[WOS]FUNCTIONALIZED POLYSUBSTITUTED FURANS ; POT REGIOSPECIFIC SYNTHESIS ; CLAISEN REARRANGEMENT ; VINYL ETHERS ; MEDICINAL CHEMISTRY ; AROMATIC-COMPOUNDS ; DOMINO ACCESS ; ENOL-ETHERS ; DERIVATIVES ; FLUORINE
英文摘要The DABCO-catalyzed reaction of propargyl alcohols with methyl 2-perfluoroalkynoate to give trifluoromethylated furans in up to 98% yield under mild conditions has been developed. The established allene-enol and control experiments indicate that the reaction should proceed through a Michael addition and Claisen rearrangement/cyclization process.
语种英语
WOS记录号WOS:000332756500023
引用统计
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/144266
专题中国科学院大连化学物理研究所
通讯作者Shi JC(施继成); Wan BS(万伯顺)
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Guangdong Univ Petrochem Technol, Coll Chem Engn, Maoming 525000, Peoples R China
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Chong, Qinglei,Xin, Xiaoyi,Wang, Chunxiang,et al. DABCO-Catalyzed Synthesis of Trifluoromethylated Furans from Propargyl Alcohols and Methyl 2-Perfluoroalkynoate[J]. JOURNAL OF ORGANIC CHEMISTRY,2014,79(5):2105-2110.
APA Chong, Qinglei.,Xin, Xiaoyi.,Wang, Chunxiang.,Wu, Fan.,Wang, Haolong.,...&万伯顺.(2014).DABCO-Catalyzed Synthesis of Trifluoromethylated Furans from Propargyl Alcohols and Methyl 2-Perfluoroalkynoate.JOURNAL OF ORGANIC CHEMISTRY,79(5),2105-2110.
MLA Chong, Qinglei,et al."DABCO-Catalyzed Synthesis of Trifluoromethylated Furans from Propargyl Alcohols and Methyl 2-Perfluoroalkynoate".JOURNAL OF ORGANIC CHEMISTRY 79.5(2014):2105-2110.
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