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学科主题: 物理化学
题名: Highly diastereo- and enantioselective copper-catalyzed propargylic alkylation of acyclic ketone enamines for the construction of two vicinal stereocenters
作者: Zhang, De-Yang1, 2;  Zhu, Fu-Lin1, 2;  Wang, Ya-Hui1;  Hu, Xin-Hu1;  Chen, Song1;  Hou, Chuan-Jin1, 3;  Hu, Xiang-Ping1
通讯作者: 胡向平
刊名: CHEMICAL COMMUNICATIONS
发表日期: 2014
DOI: 10.1039/c4cc06863g
卷: 50, 期:92, 页:14459-14462
收录类别: SCI ;  IC
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Multidisciplinary
研究领域[WOS]: Chemistry
英文摘要: The first highly diastereo- and enantioselective propargylic alkylation of acyclic ketone enamines to form vicinal tertiary stereocenters has been reported by employing copper catalysis in combination with a bulky and structurally rigid tridentate ketimine P,N,N-ligand.
关键词[WOS]: ASYMMETRIC ALLYLIC ALKYLATION ;  SUBSTITUTION-REACTIONS ;  ALPHA-ALLYLATION ;  BETA-KETOESTERS ;  AMINO-ACIDS ;  RUTHENIUM ;  ALCOHOLS ;  AMINATION ;  ALDEHYDES ;  ACETATES
语种: 英语
WOS记录号: WOS:000344244700044
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/144318
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.Dalian Polytech Univ, Dalian 116034, Peoples R China

Recommended Citation:
Zhang, De-Yang,Zhu, Fu-Lin,Wang, Ya-Hui,et al. Highly diastereo- and enantioselective copper-catalyzed propargylic alkylation of acyclic ketone enamines for the construction of two vicinal stereocenters[J]. CHEMICAL COMMUNICATIONS,2014,50(92):14459-14462.
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