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学科主题: 物理化学
题名: Enantioselective Cu-catalyzed decarboxylative propargylic amination of propargyl carbamates
作者: Zou, Yuan1, 2;  Zhu, Fu-Lin2;  Duan, Zheng-Chao3;  Wang, Ya-Hui2;  Zhang, De-Yang2;  Cao, Zhong1;  Zheng, Zhuo2;  Hu, Xiang-Ping2
通讯作者: 胡向平
关键词: Copper ;  Asymmetric catalysis ;  Decarboxylation ;  Propargylic amination ;  Propargyl carbamate
刊名: TETRAHEDRON LETTERS
发表日期: 2014-03-19
DOI: 10.1016/j.tetlet.2014.02.030
卷: 55, 期:12, 页:2033-2036
收录类别: SCI ;  IC ;  CCR
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: A copper-catalyzed asymmetric propargylic amination with a chiral ketimine P,N,N-ligand that proceeds via decarboxylation of propargyl carbamates has been developed. The reaction can be performed under the mild condition for a broad range of substrates, providing the corresponding propargylic amines in high yields and with up to 97% ee. This reaction represents a new and facile access to optically active propargylic amines. (C) 2014 Elsevier Ltd. All rights reserved.
关键词[WOS]: SUBSTITUTION-REACTIONS ;  CARBONYL GROUPS ;  AMINES ;  ACETATES ;  ESTERS ;  LIGANDS ;  IMINES ;  NUCLEOPHILES ;  ADDITIONS ;  ALKYNES
语种: 英语
WOS记录号: WOS:000334480700018
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/144319
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Changsha Univ Sci & Technol, Sch Chem & Biol Engn, Changsha 410004, Hunan, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
3.Hubei Univ Nationalities, Sch Chem & Environm Engn, Enshi 445000, Hubei, Peoples R China

Recommended Citation:
Zou, Yuan,Zhu, Fu-Lin,Duan, Zheng-Chao,et al. Enantioselective Cu-catalyzed decarboxylative propargylic amination of propargyl carbamates[J]. TETRAHEDRON LETTERS,2014,55(12):2033-2036.
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