DICP OpenIR
Subject Area物理化学
Facile preparation of polyvinyl alcohol coated SiO2 stationary phases for high performance liquid chromatography
Ji, Shunli1; Zhang, Feifang1; Wu, Shengjie1; Yang, Bingcheng1; Liang, Xinmiao1,2; Zhang FF(章飞芳); Yang BC(杨丙成)
Source PublicationANALYST
2014
DOI10.1039/c4an01021c
Volume139Issue:21Pages:5594-5599
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Analytical
WOS Research AreaChemistry
WOS KeywordHYDROPHILIC-INTERACTION CHROMATOGRAPHY ; ION CHROMATOGRAPHY ; POLAR COMPOUNDS ; SEPARATION ; RETENTION ; SILICA ; COLUMN ; ELECTROPHORESIS ; MICROSPHERES ; AMINO
AbstractA facile method to prepare a polar stationary phase for hydrophilic interaction chromatography (HILIC) was proposed by coating polyvinyl alcohol onto silica particles (PVA-Sil). A water or organic solvent-insoluble permanent PVA coating on the silica particle surface can be formed simply by dipping silica particles into a hot PVA solution and then settled from this solution, leaving a thin layer of PVA coating and frozen in a freezer. The PVA-Sil shields the silica core from solution erosion to some degree and the pH tolerance range was extended to 9.5 from 8.0 for bare silica. PVA-Sil demonstrated a good hydrophilic property for several kinds of polar compounds and similar to 57000 m(-1) of plate count was achieved. This method can also be extended as a universal method to prepare various stationary phases with exchangeable functionalities by doping the desired ingredient in a PVA solution.
Language英语
WOS IDWOS:000343003700038
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/144338
Collection中国科学院大连化学物理研究所
Corresponding AuthorZhang FF(章飞芳); Yang BC(杨丙成)
Affiliation1.East China Univ Sci Tech, Sch Pharm, Shanghai 200237, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Ji, Shunli,Zhang, Feifang,Wu, Shengjie,et al. Facile preparation of polyvinyl alcohol coated SiO2 stationary phases for high performance liquid chromatography[J]. ANALYST,2014,139(21):5594-5599.
APA Ji, Shunli.,Zhang, Feifang.,Wu, Shengjie.,Yang, Bingcheng.,Liang, Xinmiao.,...&杨丙成.(2014).Facile preparation of polyvinyl alcohol coated SiO2 stationary phases for high performance liquid chromatography.ANALYST,139(21),5594-5599.
MLA Ji, Shunli,et al."Facile preparation of polyvinyl alcohol coated SiO2 stationary phases for high performance liquid chromatography".ANALYST 139.21(2014):5594-5599.
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