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学科主题: 物理化学
题名: Dehydrogenation of primary aliphatic alcohols to aldehydes over Cu-Ni bimetallic catalysts
作者: Lu, Tianliang1, 2;  Du, Zhongtian1;  Liu, Junxia1, 2;  Chen, Chen1;  Xu, Jie1
通讯作者: 徐杰
关键词: Primary aliphatic alcohol ;  Aldehyde ;  Copper-nickel ;  Catalysis ;  Dehydrogenation
刊名: CHINESE JOURNAL OF CATALYSIS
发表日期: 2014-12-01
DOI: 10.1016/S1872-2067(14)60208-4
卷: 35, 期:12, 页:1911-1916
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences ;  Technology
类目[WOS]: Chemistry, Applied ;  Chemistry, Physical ;  Engineering, Chemical
研究领域[WOS]: Chemistry ;  Engineering
英文摘要: The catalytic conversion of non-activated primary aliphatic alcohols to aldehydes is a challenge, and monometallic Cu-based catalysts loaded on different supports have often been used for these reactions. Cu-Ni/gamma-Al2O3 bimetallic catalysts were prepared and used for anaerobic dehydrogenation of 3,3-dimethyl-1-butanol to 3,3-dimethyl-1-butanal. These catalysts exhibited higher activity than Cu/gamma-Al2O3 under the same reaction conditions, and a wide range of primary aliphatic alcohols were efficiently converted to the corresponding aldehydes over Cu-Ni/gamma-Al2O3 under mild conditions. (C) 2014, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.
关键词[WOS]: OXIDATION ;  NANOPARTICLES ;  HYDROTALCITE
语种: 英语
WOS记录号: WOS:000346395000001
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/144366
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China

Recommended Citation:
Lu, Tianliang,Du, Zhongtian,Liu, Junxia,et al. Dehydrogenation of primary aliphatic alcohols to aldehydes over Cu-Ni bimetallic catalysts[J]. CHINESE JOURNAL OF CATALYSIS,2014,35(12):1911-1916.
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