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学科主题物理化学
Efficient oxidation of ethylbenzene catalyzed by cobalt zeolitic imidazolate framework ZIF-67 and NHPI
Li, Hongyan1,2; Ma, Hong2; Wang, Xinhong1; Gao, Jin2; Chen, Chen2; Shi, Song2; Qu, Minjie1; Feng, Na1; Xu, Jie2; Xu J(徐杰)
关键词N-hydroxyphthalimide Zif-67 Oxidation Ethylbenzene Acetophenone
刊名JOURNAL OF ENERGY CHEMISTRY
2014-11-01
DOI10.1016/S2095-4956(14)60207-2
23期:6页:742-746
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences ; Technology
类目[WOS]Chemistry, Applied ; Chemistry, Physical ; Energy & Fuels ; Engineering, Chemical
研究领域[WOS]Chemistry ; Energy & Fuels ; Engineering
关键词[WOS]ROOM-TEMPERATURE SYNTHESIS ; N-HYDROXYPHTHALIMIDE NHPI ; MOLECULAR-OXYGEN ; SELECTIVE OXIDATION ; AEROBIC OXIDATION ; CARBON NANOTUBES ; COMBINATION ; PERFORMANCE ; HYDROCARBON
英文摘要Efficient catalytic oxidation of ethylbenzene to acetophenone was realized using the catalytic system of cobalt zeolitic imidazolate framework ZIF-67/N-hydroxyphthalimide (NHPI) under mild conditions. 95.2% conversion of ethylbenzene with 90.3% selectivity to acetophenone could be obtained at 373 K under 0.3 MPa o(2) for 9 h. The results show that there exists synergetic effect between ZIF-67 and NHPI. 1-Phenylethyl hydroperoxide (PEHP) was generated via a radical process involving the hydrogen abstraction from ethylbenzene by phthalimide N-oxyl, and subsequently effectively decomposed to acetophenone by ZIF-67.
语种英语
WOS记录号WOS:000346331100009
引用统计
被引频次:11[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/144367
专题中国科学院大连化学物理研究所
通讯作者Xu J(徐杰)
作者单位1.Dalian Polytech Univ, Sch Text & Mat Engn, Dalian 116034, Liaoning, Peoples R China
2.Chinese Acad Sci, State Key Lab Catalysis, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Liaoning, Peoples R China
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GB/T 7714
Li, Hongyan,Ma, Hong,Wang, Xinhong,et al. Efficient oxidation of ethylbenzene catalyzed by cobalt zeolitic imidazolate framework ZIF-67 and NHPI[J]. JOURNAL OF ENERGY CHEMISTRY,2014,23(6):742-746.
APA Li, Hongyan.,Ma, Hong.,Wang, Xinhong.,Gao, Jin.,Chen, Chen.,...&徐杰.(2014).Efficient oxidation of ethylbenzene catalyzed by cobalt zeolitic imidazolate framework ZIF-67 and NHPI.JOURNAL OF ENERGY CHEMISTRY,23(6),742-746.
MLA Li, Hongyan,et al."Efficient oxidation of ethylbenzene catalyzed by cobalt zeolitic imidazolate framework ZIF-67 and NHPI".JOURNAL OF ENERGY CHEMISTRY 23.6(2014):742-746.
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