DICP OpenIR
Subject Area物理化学
Efficient oxidation of ethylbenzene catalyzed by cobalt zeolitic imidazolate framework ZIF-67 and NHPI
Li, Hongyan1,2; Ma, Hong2; Wang, Xinhong1; Gao, Jin2; Chen, Chen2; Shi, Song2; Qu, Minjie1; Feng, Na1; Xu, Jie2; Xu J(徐杰)
KeywordN-hydroxyphthalimide Zif-67 Oxidation Ethylbenzene Acetophenone
Source PublicationJOURNAL OF ENERGY CHEMISTRY
2014-11-01
DOI10.1016/S2095-4956(14)60207-2
Volume23Issue:6Pages:742-746
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences ; Technology
WOS SubjectChemistry, Applied ; Chemistry, Physical ; Energy & Fuels ; Engineering, Chemical
WOS Research AreaChemistry ; Energy & Fuels ; Engineering
WOS KeywordROOM-TEMPERATURE SYNTHESIS ; N-HYDROXYPHTHALIMIDE NHPI ; MOLECULAR-OXYGEN ; SELECTIVE OXIDATION ; AEROBIC OXIDATION ; CARBON NANOTUBES ; COMBINATION ; PERFORMANCE ; HYDROCARBON
AbstractEfficient catalytic oxidation of ethylbenzene to acetophenone was realized using the catalytic system of cobalt zeolitic imidazolate framework ZIF-67/N-hydroxyphthalimide (NHPI) under mild conditions. 95.2% conversion of ethylbenzene with 90.3% selectivity to acetophenone could be obtained at 373 K under 0.3 MPa o(2) for 9 h. The results show that there exists synergetic effect between ZIF-67 and NHPI. 1-Phenylethyl hydroperoxide (PEHP) was generated via a radical process involving the hydrogen abstraction from ethylbenzene by phthalimide N-oxyl, and subsequently effectively decomposed to acetophenone by ZIF-67.
Language英语
WOS IDWOS:000346331100009
Citation statistics
Cited Times:13[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/144367
Collection中国科学院大连化学物理研究所
Corresponding AuthorXu J(徐杰)
Affiliation1.Dalian Polytech Univ, Sch Text & Mat Engn, Dalian 116034, Liaoning, Peoples R China
2.Chinese Acad Sci, State Key Lab Catalysis, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Liaoning, Peoples R China
Recommended Citation
GB/T 7714
Li, Hongyan,Ma, Hong,Wang, Xinhong,et al. Efficient oxidation of ethylbenzene catalyzed by cobalt zeolitic imidazolate framework ZIF-67 and NHPI[J]. JOURNAL OF ENERGY CHEMISTRY,2014,23(6):742-746.
APA Li, Hongyan.,Ma, Hong.,Wang, Xinhong.,Gao, Jin.,Chen, Chen.,...&徐杰.(2014).Efficient oxidation of ethylbenzene catalyzed by cobalt zeolitic imidazolate framework ZIF-67 and NHPI.JOURNAL OF ENERGY CHEMISTRY,23(6),742-746.
MLA Li, Hongyan,et al."Efficient oxidation of ethylbenzene catalyzed by cobalt zeolitic imidazolate framework ZIF-67 and NHPI".JOURNAL OF ENERGY CHEMISTRY 23.6(2014):742-746.
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