Asymmetric Epoxidation of Olefins with Hydrogen Peroxide by an in Situ-Formed Manganese Complex

doi:10.1021/jo501178k

DICP OpenIR

学科主题	物理化学
	Asymmetric Epoxidation of Olefins with Hydrogen Peroxide by an in Situ-Formed Manganese Complex
	Dai, Wen 1,2,3; Shang, Sensen 1,2,3; Chen, Bo 1,2,3; Li, Guosong 1,2,3; Wang, Lianyue 1,2; Ren, Lanhui 1,2,3; Gao, Shuang 1,2; Gao S(高爽)
刊名	JOURNAL OF ORGANIC CHEMISTRY
	2014-07-18
DOI	10.1021/jo501178k
卷	79 期:14 页:6688-6694
收录类别	SCI ; IC ; CCR
文章类型	Article
WOS标题词	Science & Technology ; Physical Sciences
类目[WOS]	Chemistry, Organic
研究领域[WOS]	Chemistry
关键词[WOS]	ELECTRON-DEFICIENT OLEFINS ; NONHEME IRON CATALYSTS ; ENANTIOSELECTIVE EPOXIDATION ; SYSTEM HYDROGEN ; TERMINAL OLEFINS ; (L=1,4,7-TRIMETHYL-1,4,7-TRIAZACYCLONONANE)-OXALIC ACID ; STEREOSELECTIVE EPOXIDATION ; OXIDATION CATALYSIS ; PORPHYRIN CATALYST ; CARBOXYLIC ACID
英文摘要	Asymmetric epoxidation of a variety of cis, trans, terminal, and trisubstituted olefins in excellent yields (up to 94%) and enantioselectivities (>99% cc) by an in situ-formed manganese complex using H2O2 has been developed. A relationship between the hydrophobicity of the catalyst imposed by ligand and the catalytic activity has been observed. The influence of the amount and identity of the acid additive was examined, and improved enantioselectivities were achieved through the use of a catalytic amount of a carboxylic acid additive.
语种	英语
WOS记录号	WOS:000339368300029
引用统计
文献类型	期刊论文
条目标识符	http://cas-ir.dicp.ac.cn/handle/321008/144381
专题	中国科学院大连化学物理研究所
通讯作者	Gao S(高爽)
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Dai, Wen,Shang, Sensen,Chen, Bo,et al. Asymmetric Epoxidation of Olefins with Hydrogen Peroxide by an in Situ-Formed Manganese Complex[J]. JOURNAL OF ORGANIC CHEMISTRY,2014,79(14):6688-6694.
APA	Dai, Wen.,Shang, Sensen.,Chen, Bo.,Li, Guosong.,Wang, Lianyue.,...&高爽.(2014).Asymmetric Epoxidation of Olefins with Hydrogen Peroxide by an in Situ-Formed Manganese Complex.JOURNAL OF ORGANIC CHEMISTRY,79(14),6688-6694.
MLA	Dai, Wen,et al."Asymmetric Epoxidation of Olefins with Hydrogen Peroxide by an in Situ-Formed Manganese Complex".JOURNAL OF ORGANIC CHEMISTRY 79.14(2014):6688-6694.

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