Asymmetric Epoxidation of Olefins with Hydrogen Peroxide by an in Situ-Formed Manganese Complex

doi:10.1021/jo501178k

DICP OpenIR

Subject Area	物理化学
	Asymmetric Epoxidation of Olefins with Hydrogen Peroxide by an in Situ-Formed Manganese Complex
	Dai, Wen 1,2,3; Shang, Sensen 1,2,3; Chen, Bo 1,2,3; Li, Guosong 1,2,3; Wang, Lianyue 1,2; Ren, Lanhui 1,2,3; Gao, Shuang 1,2; Gao S(高爽)
Source Publication	JOURNAL OF ORGANIC CHEMISTRY
	2014-07-18
DOI	10.1021/jo501178k
Volume	79 Issue:14 Pages:6688-6694
Indexed By	SCI ; IC ; CCR
Subtype	Article
WOS Headings	Science & Technology ; Physical Sciences
WOS Subject	Chemistry, Organic
WOS Research Area	Chemistry
WOS Keyword	ELECTRON-DEFICIENT OLEFINS ; NONHEME IRON CATALYSTS ; ENANTIOSELECTIVE EPOXIDATION ; SYSTEM HYDROGEN ; TERMINAL OLEFINS ; (L=1,4,7-TRIMETHYL-1,4,7-TRIAZACYCLONONANE)-OXALIC ACID ; STEREOSELECTIVE EPOXIDATION ; OXIDATION CATALYSIS ; PORPHYRIN CATALYST ; CARBOXYLIC ACID
Abstract	Asymmetric epoxidation of a variety of cis, trans, terminal, and trisubstituted olefins in excellent yields (up to 94%) and enantioselectivities (>99% cc) by an in situ-formed manganese complex using H2O2 has been developed. A relationship between the hydrophobicity of the catalyst imposed by ligand and the catalytic activity has been observed. The influence of the amount and identity of the acid additive was examined, and improved enantioselectivities were achieved through the use of a catalytic amount of a carboxylic acid additive.
Language	英语
WOS ID	WOS:000339368300029
Citation statistics	Cited Times:27[WOS] [WOS Record] [Related Records in WOS]
Document Type	期刊论文
Identifier	http://cas-ir.dicp.ac.cn/handle/321008/144381
Collection	中国科学院大连化学物理研究所
Corresponding Author	Gao S(高爽)
Affiliation	1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation GB/T 7714	Dai, Wen,Shang, Sensen,Chen, Bo,et al. Asymmetric Epoxidation of Olefins with Hydrogen Peroxide by an in Situ-Formed Manganese Complex[J]. JOURNAL OF ORGANIC CHEMISTRY,2014,79(14):6688-6694.
APA	Dai, Wen.,Shang, Sensen.,Chen, Bo.,Li, Guosong.,Wang, Lianyue.,...&高爽.(2014).Asymmetric Epoxidation of Olefins with Hydrogen Peroxide by an in Situ-Formed Manganese Complex.JOURNAL OF ORGANIC CHEMISTRY,79(14),6688-6694.
MLA	Dai, Wen,et al."Asymmetric Epoxidation of Olefins with Hydrogen Peroxide by an in Situ-Formed Manganese Complex".JOURNAL OF ORGANIC CHEMISTRY 79.14(2014):6688-6694.

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