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学科主题物理化学
Asymmetric Epoxidation of Olefins with Hydrogen Peroxide by an in Situ-Formed Manganese Complex
Dai, Wen1,2,3; Shang, Sensen1,2,3; Chen, Bo1,2,3; Li, Guosong1,2,3; Wang, Lianyue1,2; Ren, Lanhui1,2,3; Gao, Shuang1,2; Gao S(高爽)
刊名JOURNAL OF ORGANIC CHEMISTRY
2014-07-18
DOI10.1021/jo501178k
79期:14页:6688-6694
收录类别SCI ; IC ; CCR
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Organic
研究领域[WOS]Chemistry
关键词[WOS]ELECTRON-DEFICIENT OLEFINS ; NONHEME IRON CATALYSTS ; ENANTIOSELECTIVE EPOXIDATION ; SYSTEM HYDROGEN ; TERMINAL OLEFINS ; (L=1,4,7-TRIMETHYL-1,4,7-TRIAZACYCLONONANE)-OXALIC ACID ; STEREOSELECTIVE EPOXIDATION ; OXIDATION CATALYSIS ; PORPHYRIN CATALYST ; CARBOXYLIC ACID
英文摘要Asymmetric epoxidation of a variety of cis, trans, terminal, and trisubstituted olefins in excellent yields (up to 94%) and enantioselectivities (>99% cc) by an in situ-formed manganese complex using H2O2 has been developed. A relationship between the hydrophobicity of the catalyst imposed by ligand and the catalytic activity has been observed. The influence of the amount and identity of the acid additive was examined, and improved enantioselectivities were achieved through the use of a catalytic amount of a carboxylic acid additive.
语种英语
WOS记录号WOS:000339368300029
引用统计
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/144381
专题中国科学院大连化学物理研究所
通讯作者Gao S(高爽)
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
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GB/T 7714
Dai, Wen,Shang, Sensen,Chen, Bo,et al. Asymmetric Epoxidation of Olefins with Hydrogen Peroxide by an in Situ-Formed Manganese Complex[J]. JOURNAL OF ORGANIC CHEMISTRY,2014,79(14):6688-6694.
APA Dai, Wen.,Shang, Sensen.,Chen, Bo.,Li, Guosong.,Wang, Lianyue.,...&高爽.(2014).Asymmetric Epoxidation of Olefins with Hydrogen Peroxide by an in Situ-Formed Manganese Complex.JOURNAL OF ORGANIC CHEMISTRY,79(14),6688-6694.
MLA Dai, Wen,et al."Asymmetric Epoxidation of Olefins with Hydrogen Peroxide by an in Situ-Formed Manganese Complex".JOURNAL OF ORGANIC CHEMISTRY 79.14(2014):6688-6694.
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