DICP OpenIR
Subject Area物理化学
Asymmetric Epoxidation of Olefins with Hydrogen Peroxide by an in Situ-Formed Manganese Complex
Dai, Wen1,2,3; Shang, Sensen1,2,3; Chen, Bo1,2,3; Li, Guosong1,2,3; Wang, Lianyue1,2; Ren, Lanhui1,2,3; Gao, Shuang1,2; Gao S(高爽)
Source PublicationJOURNAL OF ORGANIC CHEMISTRY
2014-07-18
DOI10.1021/jo501178k
Volume79Issue:14Pages:6688-6694
Indexed BySCI ; IC ; CCR
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Organic
WOS Research AreaChemistry
WOS KeywordELECTRON-DEFICIENT OLEFINS ; NONHEME IRON CATALYSTS ; ENANTIOSELECTIVE EPOXIDATION ; SYSTEM HYDROGEN ; TERMINAL OLEFINS ; (L=1,4,7-TRIMETHYL-1,4,7-TRIAZACYCLONONANE)-OXALIC ACID ; STEREOSELECTIVE EPOXIDATION ; OXIDATION CATALYSIS ; PORPHYRIN CATALYST ; CARBOXYLIC ACID
AbstractAsymmetric epoxidation of a variety of cis, trans, terminal, and trisubstituted olefins in excellent yields (up to 94%) and enantioselectivities (>99% cc) by an in situ-formed manganese complex using H2O2 has been developed. A relationship between the hydrophobicity of the catalyst imposed by ligand and the catalytic activity has been observed. The influence of the amount and identity of the acid additive was examined, and improved enantioselectivities were achieved through the use of a catalytic amount of a carboxylic acid additive.
Language英语
WOS IDWOS:000339368300029
Citation statistics
Cited Times:27[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/144381
Collection中国科学院大连化学物理研究所
Corresponding AuthorGao S(高爽)
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Dai, Wen,Shang, Sensen,Chen, Bo,et al. Asymmetric Epoxidation of Olefins with Hydrogen Peroxide by an in Situ-Formed Manganese Complex[J]. JOURNAL OF ORGANIC CHEMISTRY,2014,79(14):6688-6694.
APA Dai, Wen.,Shang, Sensen.,Chen, Bo.,Li, Guosong.,Wang, Lianyue.,...&高爽.(2014).Asymmetric Epoxidation of Olefins with Hydrogen Peroxide by an in Situ-Formed Manganese Complex.JOURNAL OF ORGANIC CHEMISTRY,79(14),6688-6694.
MLA Dai, Wen,et al."Asymmetric Epoxidation of Olefins with Hydrogen Peroxide by an in Situ-Formed Manganese Complex".JOURNAL OF ORGANIC CHEMISTRY 79.14(2014):6688-6694.
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