中国科学院大连化学物理研究所机构知识库
Advanced  
DICP OpenIR  > 中国科学院大连化学物理研究所  > 期刊论文
学科主题: 物理化学
题名: Enantioselective oxidation of sulfides with H2O2 catalyzed by a pre-formed manganese complex
作者: Dai, Wen1, 2;  Li, Guosong1;  Wang, Lianyue1;  Chen, Bo1, 2;  Shang, Sensen1, 2;  Lv, Ying1;  Gao, Shuang1
通讯作者: 高爽
刊名: RSC ADVANCES
发表日期: 2014
DOI: 10.1039/c4ra09832c
卷: 4, 期:87, 页:46545-46554
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Multidisciplinary
研究领域[WOS]: Chemistry
英文摘要: A facile and environmentally friendly method is presented for the asymmetric oxidation of sulfides with H2O2, utilizing a pre-formed manganese complex. Just in the presence of a low catalytic amount of carboxylic acid (CA), a variety of sulfide substrates, including aryl alkyl, aryl benzyl and cyclic sulfides, reacted to form chiral sulfoxides in high yields (up to 95%) and excellent enantioselectivities (>99% ee) under mild conditions. Moreover, the practical utility of the method has been demonstrated by the synthesis of esomeprazole and albendazole sulfoxide (ABZO).
关键词[WOS]: ALBENDAZOLE SULFOXIDE ENANTIOMERS ;  EFFICIENT ASYMMETRIC OXIDATION ;  AQUEOUS HYDROGEN-PEROXIDE ;  ARYL BENZYL SULFIDES ;  CHIRAL SULFOXIDES ;  VANADIUM CATALYSTS ;  KINETIC RESOLUTION ;  TITANIUM CATALYST ;  EPOXIDATION ;  SYSTEM
语种: 英语
WOS记录号: WOS:000342761800022
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/144383
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

Files in This Item: Download All
File Name/ File Size Content Type Version Access License
2014PccFW6EMYV.PDF(558KB)期刊论文作者接受稿开放获取View Download

作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, Beijing 10049, Peoples R China

Recommended Citation:
Dai, Wen,Li, Guosong,Wang, Lianyue,et al. Enantioselective oxidation of sulfides with H2O2 catalyzed by a pre-formed manganese complex[J]. RSC ADVANCES,2014,4(87):46545-46554.
Service
 Recommend this item
 Sava as my favorate item
 Show this item's statistics
 Export Endnote File
Google Scholar
 Similar articles in Google Scholar
 [Dai, Wen]'s Articles
 [Li, Guosong]'s Articles
 [Wang, Lianyue]'s Articles
CSDL cross search
 Similar articles in CSDL Cross Search
 [Dai, Wen]‘s Articles
 [Li, Guosong]‘s Articles
 [Wang, Lianyue]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
  Add to CiteULike  Add to Connotea  Add to Del.icio.us  Add to Digg  Add to Reddit 
文件名: 2014PccFW6EMYV.PDF
格式: Adobe PDF
此文件暂不支持浏览
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace