DICP OpenIR
Subject Area物理化学
Catalytic conversion of carbohydrates to 5-hydroxymethylfurfural promoted by metal halides
Ren, Qiuhe1,2; Huang, Yizheng1; Ma, Hong1; Gao, Jin1; Xu, Jie1; Xu J(徐杰)
KeywordCarbohydrate 5-hydroxymethylfurfural Metal Halide Catalysis
Source PublicationCHINESE JOURNAL OF CATALYSIS
2014-04-01
DOI10.1016/51872-2067(14)60012-7
Volume35Issue:4Pages:496-500
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences ; Technology
WOS SubjectChemistry, Applied ; Chemistry, Physical ; Engineering, Chemical
WOS Research AreaChemistry ; Engineering
WOS KeywordAEROBIC OXIDATION ; LIGNOCELLULOSIC BIOMASS ; FRUCTOSE ; GLUCOSE ; CHEMICALS ; CARBON ; FUELS ; 2,5-DIFORMYLFURAN ; TRANSFORMATION ; SALTS
AbstractThe promotion effect of alkali metal halides toward the AlCl3-catalyzed conversion of glucose to 5-hydroxymethylfurfural (HMF) was investigated. The results show that NaF inhibited the reaction. However, NaI and NaBr promoted the reaction significantly, and the promotion effect of NaI was more obvious than that of NaBr. In N,N-dimethylacetamide (DMAC), when NaI was used as an additive for the AlCl3-catalyzed conversion of glucose at 130 degrees C for 15 min, glucose conversion increased from 71% to 86%, and the HMF yield increased from 36% to 62%. The AlCl3-NaI-DMAC system could also be used for the catalytic conversion of other carbohydrates such as fructose, mannose, sucrose, maltose, cellobiose, and inulin to HMF. When sucrose was used as the feedstock, a 63% HMF yield was achieved. (C) 2014, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.
Language英语
WOS IDWOS:000333781700008
Citation statistics
Cited Times:2[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/144400
Collection中国科学院大连化学物理研究所
Corresponding AuthorXu J(徐杰)
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Ren, Qiuhe,Huang, Yizheng,Ma, Hong,et al. Catalytic conversion of carbohydrates to 5-hydroxymethylfurfural promoted by metal halides[J]. CHINESE JOURNAL OF CATALYSIS,2014,35(4):496-500.
APA Ren, Qiuhe,Huang, Yizheng,Ma, Hong,Gao, Jin,Xu, Jie,&徐杰.(2014).Catalytic conversion of carbohydrates to 5-hydroxymethylfurfural promoted by metal halides.CHINESE JOURNAL OF CATALYSIS,35(4),496-500.
MLA Ren, Qiuhe,et al."Catalytic conversion of carbohydrates to 5-hydroxymethylfurfural promoted by metal halides".CHINESE JOURNAL OF CATALYSIS 35.4(2014):496-500.
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