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学科主题物理化学
Catalytic conversion of carbohydrates to 5-hydroxymethylfurfural promoted by metal halides
Ren, Qiuhe1,2; Huang, Yizheng1; Ma, Hong1; Gao, Jin1; Xu, Jie1; Xu J(徐杰)
关键词Carbohydrate 5-hydroxymethylfurfural Metal Halide Catalysis
刊名CHINESE JOURNAL OF CATALYSIS
2014-04-01
DOI10.1016/51872-2067(14)60012-7
35期:4页:496-500
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences ; Technology
类目[WOS]Chemistry, Applied ; Chemistry, Physical ; Engineering, Chemical
研究领域[WOS]Chemistry ; Engineering
关键词[WOS]AEROBIC OXIDATION ; LIGNOCELLULOSIC BIOMASS ; FRUCTOSE ; GLUCOSE ; CHEMICALS ; CARBON ; FUELS ; 2,5-DIFORMYLFURAN ; TRANSFORMATION ; SALTS
英文摘要The promotion effect of alkali metal halides toward the AlCl3-catalyzed conversion of glucose to 5-hydroxymethylfurfural (HMF) was investigated. The results show that NaF inhibited the reaction. However, NaI and NaBr promoted the reaction significantly, and the promotion effect of NaI was more obvious than that of NaBr. In N,N-dimethylacetamide (DMAC), when NaI was used as an additive for the AlCl3-catalyzed conversion of glucose at 130 degrees C for 15 min, glucose conversion increased from 71% to 86%, and the HMF yield increased from 36% to 62%. The AlCl3-NaI-DMAC system could also be used for the catalytic conversion of other carbohydrates such as fructose, mannose, sucrose, maltose, cellobiose, and inulin to HMF. When sucrose was used as the feedstock, a 63% HMF yield was achieved. (C) 2014, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.
语种英语
WOS记录号WOS:000333781700008
引用统计
被引频次:2[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/144400
专题中国科学院大连化学物理研究所
通讯作者Xu J(徐杰)
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
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GB/T 7714
Ren, Qiuhe,Huang, Yizheng,Ma, Hong,et al. Catalytic conversion of carbohydrates to 5-hydroxymethylfurfural promoted by metal halides[J]. CHINESE JOURNAL OF CATALYSIS,2014,35(4):496-500.
APA Ren, Qiuhe,Huang, Yizheng,Ma, Hong,Gao, Jin,Xu, Jie,&徐杰.(2014).Catalytic conversion of carbohydrates to 5-hydroxymethylfurfural promoted by metal halides.CHINESE JOURNAL OF CATALYSIS,35(4),496-500.
MLA Ren, Qiuhe,et al."Catalytic conversion of carbohydrates to 5-hydroxymethylfurfural promoted by metal halides".CHINESE JOURNAL OF CATALYSIS 35.4(2014):496-500.
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