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学科主题物理化学
Biphasic Catalytic Conversion of Fructose by Continuous Hydrogenation of HMF over a Hydrophobic Ruthenium Catalyst
Yang, Yanliang1,2; Du, Zhongtian1; Ma, Jiping1; Lu, Fang1; Zhang, Junjie1,2; Xu, Jie1; Xu J(徐杰)
关键词Catalysis Fructose Hydrogenation Hydrophobic Tetrahydro-2 5-furandimethanol
刊名CHEMSUSCHEM
2014-05-01
DOI10.1002/cssc.201301270
7期:5页:1352-1356
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Multidisciplinary
研究领域[WOS]Chemistry
关键词[WOS]ION-EXCHANGE-RESIN ; AEROBIC OXIDATION ; GLYCEROL HYDROGENOLYSIS ; RENEWABLE RESOURCES ; SILICA AEROGELS ; CYCLIC ETHERS ; BIOMASS ; 2,5-DIFORMYLFURAN ; CHEMICALS ; FUELS
英文摘要The production of chemicals directly from sugars is an important step in biomass conversion. Herein, tetrahydro-2,5-furandimethanol (THFDM), obtained from fructose, is formed by using a combination of acid and hydrophobic Ru/SiO2 in a water/cyclohexane biphasic system. Two key factors enable the high selectivity towards THFDM: modifying the hydrogenation catalyst so that it has hydrophobic properties, and the continuous hydrogenation of generated 5-(hydroxymethyl)furfural in the cyclohexane phase. Moreover, the selectivity towards THFDM is found to depend strongly on the acid catalyst used.
语种英语
WOS记录号WOS:000336249400015
引用统计
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/144424
专题中国科学院大连化学物理研究所
通讯作者Xu J(徐杰)
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100039, Peoples R China
推荐引用方式
GB/T 7714
Yang, Yanliang,Du, Zhongtian,Ma, Jiping,et al. Biphasic Catalytic Conversion of Fructose by Continuous Hydrogenation of HMF over a Hydrophobic Ruthenium Catalyst[J]. CHEMSUSCHEM,2014,7(5):1352-1356.
APA Yang, Yanliang.,Du, Zhongtian.,Ma, Jiping.,Lu, Fang.,Zhang, Junjie.,...&徐杰.(2014).Biphasic Catalytic Conversion of Fructose by Continuous Hydrogenation of HMF over a Hydrophobic Ruthenium Catalyst.CHEMSUSCHEM,7(5),1352-1356.
MLA Yang, Yanliang,et al."Biphasic Catalytic Conversion of Fructose by Continuous Hydrogenation of HMF over a Hydrophobic Ruthenium Catalyst".CHEMSUSCHEM 7.5(2014):1352-1356.
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