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学科主题: 物理化学
题名: Biphasic Catalytic Conversion of Fructose by Continuous Hydrogenation of HMF over a Hydrophobic Ruthenium Catalyst
作者: Yang, Yanliang1, 2;  Du, Zhongtian1;  Ma, Jiping1;  Lu, Fang1;  Zhang, Junjie1, 2;  Xu, Jie1
通讯作者: 徐杰
关键词: catalysis ;  fructose ;  hydrogenation ;  hydrophobic ;  tetrahydro-2 ;  5-furandimethanol
刊名: CHEMSUSCHEM
发表日期: 2014-05-01
DOI: 10.1002/cssc.201301270
卷: 7, 期:5, 页:1352-1356
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Multidisciplinary
研究领域[WOS]: Chemistry
英文摘要: The production of chemicals directly from sugars is an important step in biomass conversion. Herein, tetrahydro-2,5-furandimethanol (THFDM), obtained from fructose, is formed by using a combination of acid and hydrophobic Ru/SiO2 in a water/cyclohexane biphasic system. Two key factors enable the high selectivity towards THFDM: modifying the hydrogenation catalyst so that it has hydrophobic properties, and the continuous hydrogenation of generated 5-(hydroxymethyl)furfural in the cyclohexane phase. Moreover, the selectivity towards THFDM is found to depend strongly on the acid catalyst used.
关键词[WOS]: ION-EXCHANGE-RESIN ;  AEROBIC OXIDATION ;  GLYCEROL HYDROGENOLYSIS ;  RENEWABLE RESOURCES ;  SILICA AEROGELS ;  CYCLIC ETHERS ;  BIOMASS ;  2,5-DIFORMYLFURAN ;  CHEMICALS ;  FUELS
语种: 英语
WOS记录号: WOS:000336249400015
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/144424
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100039, Peoples R China

Recommended Citation:
Yang, Yanliang,Du, Zhongtian,Ma, Jiping,et al. Biphasic Catalytic Conversion of Fructose by Continuous Hydrogenation of HMF over a Hydrophobic Ruthenium Catalyst[J]. CHEMSUSCHEM,2014,7(5):1352-1356.
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