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学科主题物理化学
Synthesis of diesel range alkanes with 2-methylfuran and mesityl oxide from lignocellulose
Li, Shanshan1,2; Li, Ning1; Li, Guangyi1,2; Wang, Aiqin1; Cong, Yu1; Wang, Xiaodong1; Zhang, Tao1; Li N(李宁)
关键词Solid Acid Carbide Renewable Diesel 2-methylfuran Mesityl Oxide
刊名CATALYSIS TODAY
2014-10-01
DOI10.1016/j.cattod.2014.01.028
234期:1页:91-99
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences ; Technology
类目[WOS]Chemistry, Applied ; Chemistry, Physical ; Engineering, Chemical
研究领域[WOS]Chemistry ; Engineering
关键词[WOS]HIGH-QUALITY DIESEL ; TOLERANT SOLID ACID ; ONE-POT CONVERSION ; CATALYTIC CONVERSION ; TRANSPORTATION FUELS ; ZIRCONIUM-PHOSPHATE ; TUNGSTEN CARBIDES ; REACTION PATHWAYS ; RENEWABLE DIESEL ; ETHYLENE-GLYCOL
英文摘要For the first time, the alkylation of 2-methylfuran with mesityl oxide was carried out over a series of solid acid catalysts. Among the investigated candidates, Nafion-212 resin exhibited the highest catalytic efficiency and good stability, which can be rationalized by the higher acid strength of this catalyst. The hydrodeoxygenation (HDO) of the alkylation products of 2-methylfuran with mesityl oxide was also studied. Ni-Mo2C/SiO2 and Ni-W2C/SiO2 were firstly used for the HDO of biomass derived oxygenates and demonstrated excellent catalytic performance for the conversion of the alkylation products to alkanes. Compared with Ni-W2C/SiO2, Ni-Mo2C/SiO2 exhibited higher selectivity to diesel range alkanes. Over the Ni-Mo2C/SiO2 catalyst, high carbon yield of diesel range alkanes (77%) could be achieved by the HDO of the alkylation products of 2-methylfuran and mesityl oxide at 573 K and 6.0 MPa H-2. This value is evidently higher than those obtained over noble metal catalysts and Ni-WxC/AC under the same reaction conditions. (C) 2014 Elsevier B.V. All rights reserved.
语种英语
WOS记录号WOS:000339132900011
引用统计
被引频次:24[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/144535
专题中国科学院大连化学物理研究所
通讯作者Li N(李宁)
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
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GB/T 7714
Li, Shanshan,Li, Ning,Li, Guangyi,et al. Synthesis of diesel range alkanes with 2-methylfuran and mesityl oxide from lignocellulose[J]. CATALYSIS TODAY,2014,234(1):91-99.
APA Li, Shanshan.,Li, Ning.,Li, Guangyi.,Wang, Aiqin.,Cong, Yu.,...&李宁.(2014).Synthesis of diesel range alkanes with 2-methylfuran and mesityl oxide from lignocellulose.CATALYSIS TODAY,234(1),91-99.
MLA Li, Shanshan,et al."Synthesis of diesel range alkanes with 2-methylfuran and mesityl oxide from lignocellulose".CATALYSIS TODAY 234.1(2014):91-99.
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