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学科主题: 物理化学
题名: Production of Renewable Jet Fuel Range Branched Alkanes with Xylose and Methyl Isobutyl Ketone
作者: Pholjaroen, Boonrat1, 2;  Li, Ning1;  Yang, Jinfan1, 2;  Li, Guangyi1;  Wang, Wentao1;  Wang, Aiqin1;  Cong, Yu1;  Wang, Xiaodong1;  Zhang, Tao1
通讯作者: 李宁
刊名: INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
发表日期: 2014-09-03
DOI: 10.1021/ie5016365
卷: 53, 期:35, 页:13618-13625
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Technology
类目[WOS]: Engineering, Chemical
研究领域[WOS]: Engineering
英文摘要: A new strategy for the synthesis of jet fuel range branched alkanes with the xylose and methyl isobutyl ketone (MIBK) from lignocellulose was introduced. C-10 and C-11 branched alkanes with low freezing points were synthesized by three steps: (1) the dehydration of xylose to furfural over solid acid catalysts in MIBK/water biphasic solvent systems; (2) solid base catalyzed aldol condensation of furfural with MIBK which was also the most effective extracting solvent in the first step; (3) solvent-free hydrodeoxygenation of aldol condensation product to jet fuel range branched alkanes over Ru/H-ZSM-5 catalyst. Alternatively, oxygenated fuel can also be obtained by the low temperature hydrogenation of aldol condensation product over Ru/C catalyst.
关键词[WOS]: ALDOL-CONDENSATION ;  BIPHASIC SYSTEM ;  MILD CONDITIONS ;  SINGLE-REACTOR ;  LIQUID ALKANES ;  MIXED OXIDES ;  SOLID ACID ;  BIOMASS ;  PHASE ;  DEHYDRATION
语种: 英语
WOS记录号: WOS:000341227200008
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/144540
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China

Recommended Citation:
Pholjaroen, Boonrat,Li, Ning,Yang, Jinfan,et al. Production of Renewable Jet Fuel Range Branched Alkanes with Xylose and Methyl Isobutyl Ketone[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,2014,53(35):13618-13625.
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