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Promoted role of Cu(NO3)(2) on aerobic oxidation of 5-hydroxymethylfurfural to 2,5-diformylfuran over VOSO4
Jia, Xiuquan1,2; Ma, Jiping1; Wang, Min1; Du, Zhongtian1; Lu, Fang1; Wang, Feng1; Xu, Jie1
KeywordCatalysis Copper Nitrate Oxidation 2 Sustainable Chemistry 5-diformylfuran
Source PublicationAPPLIED CATALYSIS A-GENERAL
2014-07-22
DOI10.1016/j.apcata.2014.05.031
Volume482Pages:231-236
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences ; Life Sciences & Biomedicine
WOS SubjectChemistry, Physical ; Environmental Sciences
WOS Research AreaChemistry ; Environmental Sciences & Ecology
WOS KeywordSELECTIVE OXIDATION ; ONE-POT ; LIGNOCELLULOSIC BIOMASS ; CATALYTIC CONVERSION ; RENEWABLE RESOURCES ; SUPPORTED RUTHENIUM ; MOLECULAR-OXYGEN ; VANADYL SULFATE ; MILD CONDITIONS ; ALKYL RADICALS
AbstractThe promoted effect of Cu(NO3)(2) on aerobic oxidation of 5-hydroxymethylfurfural (HMF) to 2,5-diformylfuran (DFF) catalyzed by VOSO4 in acetonitrile was intensively investigated. It was revealed that Cu(NO3)(2) facilitated the activation of VOSO4 to generate active V5+ species via the generation of NO gas. The high OFF selectivity is ascribed to Cu2+ cation which can effectively prohibit oxidative C-C bond cleavage reaction of HMF and prevent radical reaction of OFF to humins. In addition, the polarity of solvent plays a great role on high selectivity of OFF. (C) 2014 Elsevier B.V. All rights reserved.
Language英语
WOS IDWOS:000340306500028
Citation statistics
Cited Times:25[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/145401
Collection中国科学院大连化学物理研究所
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Jia, Xiuquan,Ma, Jiping,Wang, Min,et al. Promoted role of Cu(NO3)(2) on aerobic oxidation of 5-hydroxymethylfurfural to 2,5-diformylfuran over VOSO4[J]. APPLIED CATALYSIS A-GENERAL,2014,482:231-236.
APA Jia, Xiuquan.,Ma, Jiping.,Wang, Min.,Du, Zhongtian.,Lu, Fang.,...&Xu, Jie.(2014).Promoted role of Cu(NO3)(2) on aerobic oxidation of 5-hydroxymethylfurfural to 2,5-diformylfuran over VOSO4.APPLIED CATALYSIS A-GENERAL,482,231-236.
MLA Jia, Xiuquan,et al."Promoted role of Cu(NO3)(2) on aerobic oxidation of 5-hydroxymethylfurfural to 2,5-diformylfuran over VOSO4".APPLIED CATALYSIS A-GENERAL 482(2014):231-236.
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