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题名: Promoted role of Cu(NO3)(2) on aerobic oxidation of 5-hydroxymethylfurfural to 2,5-diformylfuran over VOSO4
作者: Jia, Xiuquan1, 2;  Ma, Jiping1;  Wang, Min1;  Du, Zhongtian1;  Lu, Fang1;  Wang, Feng1;  Xu, Jie1
关键词: Catalysis ;  Copper nitrate ;  2,5-Diformylfuran ;  Oxidation ;  Sustainable chemistry
刊名: APPLIED CATALYSIS A-GENERAL
发表日期: 2014-07-22
DOI: 10.1016/j.apcata.2014.05.031
卷: 482, 页:231-236
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences ;  Life Sciences & Biomedicine
类目[WOS]: Chemistry, Physical ;  Environmental Sciences
研究领域[WOS]: Chemistry ;  Environmental Sciences & Ecology
英文摘要: The promoted effect of Cu(NO3)(2) on aerobic oxidation of 5-hydroxymethylfurfural (HMF) to 2,5-diformylfuran (DFF) catalyzed by VOSO4 in acetonitrile was intensively investigated. It was revealed that Cu(NO3)(2) facilitated the activation of VOSO4 to generate active V5+ species via the generation of NO gas. The high OFF selectivity is ascribed to Cu2+ cation which can effectively prohibit oxidative C-C bond cleavage reaction of HMF and prevent radical reaction of OFF to humins. In addition, the polarity of solvent plays a great role on high selectivity of OFF. (C) 2014 Elsevier B.V. All rights reserved.
关键词[WOS]: SELECTIVE OXIDATION ;  ONE-POT ;  LIGNOCELLULOSIC BIOMASS ;  CATALYTIC CONVERSION ;  RENEWABLE RESOURCES ;  SUPPORTED RUTHENIUM ;  MOLECULAR-OXYGEN ;  VANADYL SULFATE ;  MILD CONDITIONS ;  ALKYL RADICALS
语种: 英语
WOS记录号: WOS:000340306500028
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/145401
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China

Recommended Citation:
Jia, Xiuquan,Ma, Jiping,Wang, Min,et al. Promoted role of Cu(NO3)(2) on aerobic oxidation of 5-hydroxymethylfurfural to 2,5-diformylfuran over VOSO4[J]. APPLIED CATALYSIS A-GENERAL,2014,482:231-236.
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