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题名: Cu-Catalyzed Ring Opening Reaction of 2H-Azirines with Terminal Alkynes: An Easy Access to 3-Alkynylated Pyrroles
作者: Li, Tengfei1;  Xin, Xiaoyi1;  Wang, Chunxiang1;  Wang, Dongping1;  Wu, Fan1;  Li, Xincheng1;  Wan, Boshun1
刊名: ORGANIC LETTERS
发表日期: 2014-09-19
DOI: 10.1021/ol502282j
卷: 16, 期:18, 页:4806-4809
收录类别: SCI ;  IC ;  CCR
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: A highly efficient Cu-catalyzed ring expansion reaction of 2H-azirines with terminal alkynes has been developed. This transformation provides a powerful method for the synthesis of 3-alkynyl polysubstituted pyrroles under mild conditions in good yields. The direct transformation process, specific selectivity, and good tolerance to a variety of substituents make it an alternative approach to the reported protocols.
关键词[WOS]: FUNCTIONALIZED PYRROLES ;  DIRECT ALKYNYLATION ;  REGIOSELECTIVE SYNTHESIS ;  SUBSTITUTED PYRROLES ;  3+2 CYCLOADDITION ;  VINYL AZIDES ;  HETEROCYCLES ;  CHEMISTRY ;  INDOLES ;  DERIVATIVES
语种: 英语
WOS记录号: WOS:000342117600029
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/145435
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

Recommended Citation:
Li, Tengfei,Xin, Xiaoyi,Wang, Chunxiang,et al. Cu-Catalyzed Ring Opening Reaction of 2H-Azirines with Terminal Alkynes: An Easy Access to 3-Alkynylated Pyrroles[J]. ORGANIC LETTERS,2014,16(18):4806-4809.
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