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Cu-Catalyzed Ring Opening Reaction of 2H-Azirines with Terminal Alkynes: An Easy Access to 3-Alkynylated Pyrroles
Li, Tengfei; Xin, Xiaoyi; Wang, Chunxiang; Wang, Dongping; Wu, Fan; Li, Xincheng; Wan, Boshun
Source PublicationORGANIC LETTERS
2014-09-19
DOI10.1021/ol502282j
Volume16Issue:18Pages:4806-4809
Indexed BySCI ; IC ; CCR
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Organic
WOS Research AreaChemistry
WOS KeywordFUNCTIONALIZED PYRROLES ; DIRECT ALKYNYLATION ; REGIOSELECTIVE SYNTHESIS ; SUBSTITUTED PYRROLES ; 3+2 CYCLOADDITION ; VINYL AZIDES ; HETEROCYCLES ; CHEMISTRY ; INDOLES ; DERIVATIVES
AbstractA highly efficient Cu-catalyzed ring expansion reaction of 2H-azirines with terminal alkynes has been developed. This transformation provides a powerful method for the synthesis of 3-alkynyl polysubstituted pyrroles under mild conditions in good yields. The direct transformation process, specific selectivity, and good tolerance to a variety of substituents make it an alternative approach to the reported protocols.
Language英语
WOS IDWOS:000342117600029
Citation statistics
Cited Times:41[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/145435
Collection中国科学院大连化学物理研究所
AffiliationChinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Li, Tengfei,Xin, Xiaoyi,Wang, Chunxiang,et al. Cu-Catalyzed Ring Opening Reaction of 2H-Azirines with Terminal Alkynes: An Easy Access to 3-Alkynylated Pyrroles[J]. ORGANIC LETTERS,2014,16(18):4806-4809.
APA Li, Tengfei.,Xin, Xiaoyi.,Wang, Chunxiang.,Wang, Dongping.,Wu, Fan.,...&Wan, Boshun.(2014).Cu-Catalyzed Ring Opening Reaction of 2H-Azirines with Terminal Alkynes: An Easy Access to 3-Alkynylated Pyrroles.ORGANIC LETTERS,16(18),4806-4809.
MLA Li, Tengfei,et al."Cu-Catalyzed Ring Opening Reaction of 2H-Azirines with Terminal Alkynes: An Easy Access to 3-Alkynylated Pyrroles".ORGANIC LETTERS 16.18(2014):4806-4809.
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