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Enhancement of Solar Hydrogen Evolution from Water by Surface Modification with CdS and TiO2 on Porous CuInS2 Photocathodes Prepared by an Electrodeposition-Sulfurization Method
Zhao, Jiao1,2,3; Minegishi, Tsutomu1; Zhang, Li1; Zhong, Miao2,4; Gunawan; Nakabayashi, Mamiko6; Ma, Guijun2,4; Hisatomi, Takashi1; Katayama, Masao1; Ikeda, Shigeru5; Shibata, Naoya6; Yamada, Taro4; Domen, Kazunari1
关键词Electrodeposition Hydrogen Production I-iii-vi2 Chalcopyrites Photocathodes Photoelectrochemistry
刊名ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
2014-10-27
DOI10.1002/anie.201406483
53期:44页:11808-11812
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Multidisciplinary
研究领域[WOS]Chemistry
关键词[WOS]VISIBLE-LIGHT ; CELLS ; PHOTOABSORBER ; FABRICATION ; LAYERS
英文摘要Porous films of p-type CuInS2, prepared by sulfurization of electrodeposited metals, are surface-modified with thin layers of CdS and TiO2. This specific porous electrode evolved H-2 from photoelectrochemical water reduction under simulated sunlight. Modification with thin n-type CdS and TiO2 layers significantly increased the cathodic photocurrent and onset potential through the formation of a p-n junction on the surface. The modified photocathodes showed a relatively high efficiency and stable H-2 production under the present reaction conditions.
语种英语
WOS记录号WOS:000344050700015
引用统计
被引频次:82[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/145443
专题中国科学院大连化学物理研究所
作者单位1.Univ Tokyo, Dept Chem Syst Engn, Bunkyo Ku, Tokyo 1138656, Japan
2.Artificial Photosynthet Chem Proc ARPChem, Japan Technol Res Assoc, Kashiwa, Chiba 2778589, Japan
3.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
4.Univ Tokyo, Dept Chem Syst Engn, Kashiwa, Chiba 2778589, Japan
5.Osaka Univ, Res Ctr Solar Energy Chem, Toyonaka, Osaka 5608531, Japan
6.Univ Tokyo, Inst Engn Innovat, Bunkyo Ku, Tokyo 1138656, Japan
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GB/T 7714
Zhao, Jiao,Minegishi, Tsutomu,Zhang, Li,et al. Enhancement of Solar Hydrogen Evolution from Water by Surface Modification with CdS and TiO2 on Porous CuInS2 Photocathodes Prepared by an Electrodeposition-Sulfurization Method[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2014,53(44):11808-11812.
APA Zhao, Jiao.,Minegishi, Tsutomu.,Zhang, Li.,Zhong, Miao.,Gunawan.,...&Domen, Kazunari.(2014).Enhancement of Solar Hydrogen Evolution from Water by Surface Modification with CdS and TiO2 on Porous CuInS2 Photocathodes Prepared by an Electrodeposition-Sulfurization Method.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,53(44),11808-11812.
MLA Zhao, Jiao,et al."Enhancement of Solar Hydrogen Evolution from Water by Surface Modification with CdS and TiO2 on Porous CuInS2 Photocathodes Prepared by an Electrodeposition-Sulfurization Method".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 53.44(2014):11808-11812.
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