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题名: Rhodium(III)-catalyzed coupling of N-sulfonyl 2-aminobenzaldehydes with oxygenated allylic olefins through C-H activation
作者: Yang, Tingting2, 3;  Zhang, Tao2;  Yang, Shangdong3;  Chen, Shanshan1;  Li, Xingwei2
刊名: ORGANIC & BIOMOLECULAR CHEMISTRY
发表日期: 2014
DOI: 10.1039/c4ob00704b
卷: 12, 期:25, 页:4290-4294
收录类别: SCI ;  IC ;  CCR
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: Rh(III)-catalyzed coupling of N-sulfonyl 2-aminobenzaldehydes with oxygenated allylic olefins via C-H bond activation is described. Diarylketones were obtained through coupling of N-sulfonyl 2-aminobenzaldehydes with 7-oxabenzonorbornadienes. On the other hand, the coupling with allyl carbonate yielded a six-membered sulfonyl lactam via a sequence of allylation-isomerization-Michael cyclization.
关键词[WOS]: RING-OPENING REACTIONS ;  OXABICYCLIC ALKENES ;  BOND ACTIVATION ;  INTERMOLECULAR HYDROACYLATION ;  ASYMMETRIC-SYNTHESIS ;  ANTITUMOR AGENTS ;  CATALYST SYSTEM ;  DIRECTING GROUP ;  PALLADIUM ;  CLEAVAGE
语种: 英语
WOS记录号: WOS:000337129000002
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/145444
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Anhui Agr Univ, Sch Nat Sci, Hefei 230036, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
3.Lanzhou Univ, Coll Chem & Chem Engn, Lanzhou 730000, Peoples R China

Recommended Citation:
Yang, Tingting,Zhang, Tao,Yang, Shangdong,et al. Rhodium(III)-catalyzed coupling of N-sulfonyl 2-aminobenzaldehydes with oxygenated allylic olefins through C-H activation[J]. ORGANIC & BIOMOLECULAR CHEMISTRY,2014,12(25):4290-4294.
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