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Velocity Map Imaging Study of the Reaction Dynamics of the H + CH4 -> H-2 + CH3 Reaction: The Isotope Effects
Pan, Huilin1; Yang, Jiayue1; Shuai, Quan1; Zhang, Dong1; Zhang, Weiqing1,2; Wu, Guorong1,2; Dai, Dongxu1,2; Jiang, Bo1; Zhang, Donghui1,2; Yang, Xueming1,2
刊名JOURNAL OF PHYSICAL CHEMISTRY A
2014-04-03
DOI10.1021/jp501681h
118期:13页:2426-2430
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Physical ; Physics, Atomic, Molecular & Chemical
研究领域[WOS]Chemistry ; Physics
关键词[WOS]POTENTIAL-ENERGY SURFACE ; ABSTRACTION REACTION DYNAMICS ; SIMPLEST REACTION ; QUANTUM DYNAMICS ; CARBON-ATOM
英文摘要Following our previous study on the H + CD4 -> HD + CD3 reaction [Proc. Natl. Acad. Sci. U.S.A. 2010, 107, 12782], the reaction of H + CH4 -> H-2 + CH3 at collision energies ranging from 0.72 to 1.99 eV is studied using crossed-beam and time-sliced velocity map ion imaging techniques. The product angular and translational energy distributions at four different collision energies were derived from the measured images. The excitation function was also measured from these images together with a careful calibration of the H atom beam intensities at different collision energies. All of these results are compared with those of the H + CD4 reaction to investigate the isotope effects. The isotope effects are all observed in the product angular distributions, the translational energy distributions, and the excitation function and further confirm the reaction mechanism proposed in the previous study on the H + CD4 reaction.
语种英语
WOS记录号WOS:000333948100006
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文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/145468
专题中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Liaoning, Peoples R China
2.Univ Sci & Technol China, Synerget Innovat Ctr Quantum Informat & Quantum P, Hefei 230026, Anhui, Peoples R China
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Pan, Huilin,Yang, Jiayue,Shuai, Quan,et al. Velocity Map Imaging Study of the Reaction Dynamics of the H + CH4 -> H-2 + CH3 Reaction: The Isotope Effects[J]. JOURNAL OF PHYSICAL CHEMISTRY A,2014,118(13):2426-2430.
APA Pan, Huilin.,Yang, Jiayue.,Shuai, Quan.,Zhang, Dong.,Zhang, Weiqing.,...&Yang, Xueming.(2014).Velocity Map Imaging Study of the Reaction Dynamics of the H + CH4 -> H-2 + CH3 Reaction: The Isotope Effects.JOURNAL OF PHYSICAL CHEMISTRY A,118(13),2426-2430.
MLA Pan, Huilin,et al."Velocity Map Imaging Study of the Reaction Dynamics of the H + CH4 -> H-2 + CH3 Reaction: The Isotope Effects".JOURNAL OF PHYSICAL CHEMISTRY A 118.13(2014):2426-2430.
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