DICP OpenIR
Velocity Map Imaging Study of the Reaction Dynamics of the H + CH4 -> H-2 + CH3 Reaction: The Isotope Effects
Pan, Huilin1; Yang, Jiayue1; Shuai, Quan1; Zhang, Dong1; Zhang, Weiqing1,2; Wu, Guorong1,2; Dai, Dongxu1,2; Jiang, Bo1; Zhang, Donghui1,2; Yang, Xueming1,2
Source PublicationJOURNAL OF PHYSICAL CHEMISTRY A
2014-04-03
DOI10.1021/jp501681h
Volume118Issue:13Pages:2426-2430
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Physical ; Physics, Atomic, Molecular & Chemical
WOS Research AreaChemistry ; Physics
WOS KeywordPOTENTIAL-ENERGY SURFACE ; ABSTRACTION REACTION DYNAMICS ; SIMPLEST REACTION ; QUANTUM DYNAMICS ; CARBON-ATOM
AbstractFollowing our previous study on the H + CD4 -> HD + CD3 reaction [Proc. Natl. Acad. Sci. U.S.A. 2010, 107, 12782], the reaction of H + CH4 -> H-2 + CH3 at collision energies ranging from 0.72 to 1.99 eV is studied using crossed-beam and time-sliced velocity map ion imaging techniques. The product angular and translational energy distributions at four different collision energies were derived from the measured images. The excitation function was also measured from these images together with a careful calibration of the H atom beam intensities at different collision energies. All of these results are compared with those of the H + CD4 reaction to investigate the isotope effects. The isotope effects are all observed in the product angular distributions, the translational energy distributions, and the excitation function and further confirm the reaction mechanism proposed in the previous study on the H + CD4 reaction.
Language英语
WOS IDWOS:000333948100006
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/145468
Collection中国科学院大连化学物理研究所
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Liaoning, Peoples R China
2.Univ Sci & Technol China, Synerget Innovat Ctr Quantum Informat & Quantum P, Hefei 230026, Anhui, Peoples R China
Recommended Citation
GB/T 7714
Pan, Huilin,Yang, Jiayue,Shuai, Quan,et al. Velocity Map Imaging Study of the Reaction Dynamics of the H + CH4 -> H-2 + CH3 Reaction: The Isotope Effects[J]. JOURNAL OF PHYSICAL CHEMISTRY A,2014,118(13):2426-2430.
APA Pan, Huilin.,Yang, Jiayue.,Shuai, Quan.,Zhang, Dong.,Zhang, Weiqing.,...&Yang, Xueming.(2014).Velocity Map Imaging Study of the Reaction Dynamics of the H + CH4 -> H-2 + CH3 Reaction: The Isotope Effects.JOURNAL OF PHYSICAL CHEMISTRY A,118(13),2426-2430.
MLA Pan, Huilin,et al."Velocity Map Imaging Study of the Reaction Dynamics of the H + CH4 -> H-2 + CH3 Reaction: The Isotope Effects".JOURNAL OF PHYSICAL CHEMISTRY A 118.13(2014):2426-2430.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Pan, Huilin]'s Articles
[Yang, Jiayue]'s Articles
[Shuai, Quan]'s Articles
Baidu academic
Similar articles in Baidu academic
[Pan, Huilin]'s Articles
[Yang, Jiayue]'s Articles
[Shuai, Quan]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Pan, Huilin]'s Articles
[Yang, Jiayue]'s Articles
[Shuai, Quan]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.