中国科学院大连化学物理研究所机构知识库
Advanced  
DICP OpenIR  > 中国科学院大连化学物理研究所  > 期刊论文
题名: Synthesis, structure characterization, and thermochemistry of the coordination compounds of pyridine-2,6-dicarboxylic acid with several metals (Ca and Co)
作者: Gao, Z. F.1;  Di, Y. Y.1;  Tan, Z. C.2;  Dou, J. M.1
关键词: Complexes of pyridine-2,6-dicarboxylic acid with Ca2+ and Co2+ ions ;  Crystal structure ;  Adiabatic calorimetry ;  Low-temperature heat capacity ;  Thermodynamic function
刊名: JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
发表日期: 2014-02-01
DOI: 10.1007/s10973-013-3479-3
卷: 115, 期:2, 页:1205-1210
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Analytical ;  Chemistry, Physical
研究领域[WOS]: Chemistry
英文摘要: Two solid state complexes of pyridine-2,6-dicarboxylate with Ca2+ and Co2+ ions, Ca-2(DPC)(2)(H2O)(6)(H2DPC)(2)(s) and Co(DPC)(2)center dot Co(H2O)(5)center dot 2H(2)O(s), were synthesized. X-ray crystallography was applied to characterize the crystal structures of the two complexes. The molecular and cell stacking structures of the two complexes were shown; the crystal data and refinement details were summarized, and the selected bond lengths and angles of the title complexes were listed. Low-temperature heat capacities of the two complexes were measured with an automated adiabatic calorimeter in the temperature ranging from 78 to 380 K. Two polynomial equations of experimental molar heat capacities as a function of the temperature were obtained by the least-squares method. The smoothed molar heat capacities and thermodynamic functions of the complexes were calculated based on the fitted polynomial equations. In addition, thermodynamic properties of the two complexes were compared.
关键词[WOS]: HEAT-CAPACITY ;  THERMODYNAMIC PROPERTIES
语种: 英语
WOS记录号: WOS:000330729100026
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/145480
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

Files in This Item:

There are no files associated with this item.


作者单位: 1.Liaocheng Univ, Shandong Prov Key Lab Chem Energy Storage & Novel, Coll Chem & Chem Engn, Liaocheng 252059, Shandong, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Thermochem Lab, Dalian 116023, Peoples R China

Recommended Citation:
Gao, Z. F.,Di, Y. Y.,Tan, Z. C.,et al. Synthesis, structure characterization, and thermochemistry of the coordination compounds of pyridine-2,6-dicarboxylic acid with several metals (Ca and Co)[J]. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY,2014,115(2):1205-1210.
Service
 Recommend this item
 Sava as my favorate item
 Show this item's statistics
 Export Endnote File
Google Scholar
 Similar articles in Google Scholar
 [Gao, Z. F.]'s Articles
 [Di, Y. Y.]'s Articles
 [Tan, Z. C.]'s Articles
CSDL cross search
 Similar articles in CSDL Cross Search
 [Gao, Z. F.]‘s Articles
 [Di, Y. Y.]‘s Articles
 [Tan, Z. C.]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
  Add to CiteULike  Add to Connotea  Add to Del.icio.us  Add to Digg  Add to Reddit 
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace