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题名: Mild Synthesis of Chalcones via Rhodium(III)-Catalyzed C-C Coupling of Arenes and Cyclopropenones
作者: Yu, Songjie1;  Li, Xingwei1
刊名: ORGANIC LETTERS
发表日期: 2014-02-21
DOI: 10.1021/ol500140e
卷: 16, 期:4, 页:1220-1223
收录类别: SCI ;  IC ;  CCR
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: A Rh(III)-catalyzed aryl C-H bond insertion into cyclopropenones via a C-H activation pathway has been reported. A series of arenes bearing directing groups such as 2-pyridyl, 2-pyrimidyl, N-pyrazyl, and oxime can be applicable, providing chalcones in excellent yields under mild conditions. Several possible Rh(III) intermediates in this reaction were investigated.
关键词[WOS]: H BOND ACTIVATION ;  CONVERGENT SYNTHESIS ;  CATALYZED SYNTHESIS ;  RHODIUM CATALYSIS ;  3+2 CYCLOADDITION ;  DIRECTING GROUP ;  FUNCTIONALIZATION ;  CLEAVAGE ;  ALKYNES ;  ARYL
语种: 英语
WOS记录号: WOS:000331926800048
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/145486
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

Recommended Citation:
Yu, Songjie,Li, Xingwei. Mild Synthesis of Chalcones via Rhodium(III)-Catalyzed C-C Coupling of Arenes and Cyclopropenones[J]. ORGANIC LETTERS,2014,16(4):1220-1223.
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