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题名: N-Heterocyclic Carbene Organocatalytic Reductive beta,beta-Coupling Reactions of Nitroalkenes via Radical Intermediates
作者: Du, Yu1;  Wang, Yuhuang1;  Li, Xin2;  Shao, Yaling1;  Li, Guohui2;  Webster, Richard D.1;  Chi, Yonggui Robin1
刊名: ORGANIC LETTERS
发表日期: 2014-11-07
DOI: 10.1021/ol5027415
卷: 16, 期:21, 页:5678-5681
收录类别: SCI ;  IC ;  CCR
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: An unprecedented N-heterocyclic carbene catalytic reductive beta,beta-carbon coupling of alpha,beta-nitroalkenes, by using an organic substrate to mimic the one-electron oxidation role of the pyruvate ferredoxin oxidoreductase (PFOR) in living systems, has been developed. The reaction goes through a radical anion intermediate generated under a catalytic redox process. For the first time, the presence of radical anion intermediate in NHC organocatalysis is observed and clearly verified.
关键词[WOS]: PYRUVATE-FERREDOXIN OXIDOREDUCTASE ;  INTERMOLECULAR STETTER REACTION ;  ACTIVATED DOUBLE-BONDS ;  OXIDATIVE ESTERIFICATION ;  MEDIATED REDUCTION ;  STEREOSELECTIVE-SYNTHESIS ;  CATALYZED OXIDATIONS ;  ALIPHATIC-ALDEHYDES ;  BENZOIN REACTIONS ;  ESTERS
语种: 英语
WOS记录号: WOS:000344635200044
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/145494
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Nanyang Technol Univ, Sch Phys & Math Sci, Div Chem & Biol Chem, Singapore 637371, Singapore
2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China

Recommended Citation:
Du, Yu,Wang, Yuhuang,Li, Xin,et al. N-Heterocyclic Carbene Organocatalytic Reductive beta,beta-Coupling Reactions of Nitroalkenes via Radical Intermediates[J]. ORGANIC LETTERS,2014,16(21):5678-5681.
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