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题名: Thermal Methane Activation by La6O10-Cluster Anions
作者: Meng, Jing-Heng1, 3;  Deng, Xiao-Jiao2, 3;  Li, Zi-Yu1, 3;  He, Sheng-Gui1;  Zheng, Wei-Jun2
关键词: CH activation ;  density functional calculations ;  mass spectrometry ;  oxide cluster anions ;  reaction mechanisms
刊名: CHEMISTRY-A EUROPEAN JOURNAL
发表日期: 2014-05-05
DOI: 10.1002/chem.201400218
卷: 20, 期:19, 页:5580-5583
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Multidisciplinary
研究领域[WOS]: Chemistry
英文摘要: The first example of a metal oxide cluster anion, La6O10- that can activate methane under ambient conditions is reported. This reaction is facilitated by the oxygen-centered radical (O-) and follows the hydrogen atom transfer mechanism. The La6O10- has a high vertical electron detachment energy (VDE=4.06eV) and a high symmetry (C-4v).
关键词[WOS]: OXIDE CLUSTER CATIONS ;  H BOND ACTIVATION ;  CATALYTIC-OXIDATION REACTIONS ;  LANTHANUM OXIDE ;  GAS-PHASE ;  IONS ;  SURFACES ;  CENTERS ;  LA2O3 ;  GENERATION
语种: 英语
WOS记录号: WOS:000335197000010
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/145511
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Inst Chem, State Key Lab Struct Chem Unstable & Stable Speci, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
2.Chinese Acad Sci, Inst Chem, State Key Lab Mol React Dynam, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China

Recommended Citation:
Meng, Jing-Heng,Deng, Xiao-Jiao,Li, Zi-Yu,et al. Thermal Methane Activation by La6O10-Cluster Anions[J]. CHEMISTRY-A EUROPEAN JOURNAL,2014,20(19):5580-5583.
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