中国科学院大连化学物理研究所机构知识库
Advanced  
DICP OpenIR  > 中国科学院大连化学物理研究所  > 期刊论文
题名: Lithiated Primary Amine-A New Material for Hydrogen Storage
作者: Chen, Juner1, 2;  Wu, Hui3, 4;  Wu, Guotao1;  Xiong, Zhitao1;  Wang, Ruiming1;  Fan, Hongjun1;  Zhou, Wei3, 4;  Liu, Bin1;  Chua, Yongshen1;  Ju, Xiaohua1;  Chen, Ping1
关键词: dehydrogenation ;  hydrogen storage ;  lithiated amines ;  organometallic chemistry ;  -elimination
刊名: CHEMISTRY-A EUROPEAN JOURNAL
发表日期: 2014-05-26
DOI: 10.1002/chem.201402543
卷: 20, 期:22, 页:6632-6635
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Multidisciplinary
研究领域[WOS]: Chemistry
英文摘要: A facile method for synthesizing crystalline lithiated amines by ball milling primary amines with LiH was developed. The lithiated amines exhibit an unprecedented endothermic dehydrogenation feature in the temperature range of 150-250 degrees C, which shows potential as a new type of hydrogen storage material. Structural analysis and mechanistic studies on lithiated ethylenediamine (Li(2)EDA) indicates that Li may mediate the dehydrogenation through an ,-LiH elimination mechanism, creating a more energy favorable pathway for the selective H-2 release.
关键词[WOS]: OXIDATIVE DEHYDROGENATION ;  PINCER COMPLEXES ;  METAL ;  CATALYSTS ;  LITHIUM ;  DECOMPOSITION ;  MOLYBDENUM ;  ACTIVATION ;  MECHANISM ;  NITRILES
语种: 英语
WOS记录号: WOS:000336002200010
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/145514
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

Files in This Item:

There are no files associated with this item.


作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.NIST, Ctr Neutron Res, Gaithersburg, MD 20899 USA
4.Univ Maryland, Dept Mat Sci & Engn, College Pk, MD 20742 USA

Recommended Citation:
Chen, Juner,Wu, Hui,Wu, Guotao,et al. Lithiated Primary Amine-A New Material for Hydrogen Storage[J]. CHEMISTRY-A EUROPEAN JOURNAL,2014,20(22):6632-6635.
Service
 Recommend this item
 Sava as my favorate item
 Show this item's statistics
 Export Endnote File
Google Scholar
 Similar articles in Google Scholar
 [Chen, Juner]'s Articles
 [Wu, Hui]'s Articles
 [Wu, Guotao]'s Articles
CSDL cross search
 Similar articles in CSDL Cross Search
 [Chen, Juner]‘s Articles
 [Wu, Hui]‘s Articles
 [Wu, Guotao]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
  Add to CiteULike  Add to Connotea  Add to Del.icio.us  Add to Digg  Add to Reddit 
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace