DICP OpenIR
Efficient Fixation of CO2 by a Zinc-Coordinated Conjugated Microporous Polymer
Xie, Yong1,2; Wang, Ting-Ting2; Yang, Rui-Xia2; Huang, Nian-Yu1; Zou, Kun1; Deng, Wei-Qiao2
KeywordCo(2) Fixation Cyclic Carbonates Heterogeneous Catalysis Turnover Frequencies Polymers
Source PublicationCHEMSUSCHEM
2014-08-01
DOI10.1002/cssc.201402162
Volume7Issue:8Pages:2110-2114
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Multidisciplinary
WOS Research AreaChemistry
WOS KeywordCYCLIC CARBONATE SYNTHESIS ; POROUS ORGANIC POLYMERS ; HIGH-SURFACE-AREA ; COUPLING REACTIONS ; SALEN COMPLEXES ; MILD CONDITIONS ; IONIC LIQUIDS ; EPOXIDES ; DIOXIDE ; CATALYST
AbstractZinc-coordinated conjugated microporous polymers (Zn-CMPs), prepared by linking salen zinc and 1,3,5-triethynylbenzene, exhibit extraordinary activities (turnover frequencies of up to 11600 h(-1)), broad substrate scope, and group tolerance for the synthesis of functional organic carbonates by coupling epoxides with CO2 at 120 degrees C and 3.0 MPa without the use of additional solvents. The catalytic activity of Zn-CMP is comparable to those of homogeneous catalysts and superior to those of other heterogeneous catalysts. This catalyst could be reused more than ten times without a significant decrease in performance.
Language英语
WOS IDWOS:000340519500007
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/145526
Collection中国科学院大连化学物理研究所
Affiliation1.China Three Gorges Univ, Hubei Key Lab Nat Prod Res, Coll Chem & Life Sci, Yichang 443002, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Xie, Yong,Wang, Ting-Ting,Yang, Rui-Xia,et al. Efficient Fixation of CO2 by a Zinc-Coordinated Conjugated Microporous Polymer[J]. CHEMSUSCHEM,2014,7(8):2110-2114.
APA Xie, Yong,Wang, Ting-Ting,Yang, Rui-Xia,Huang, Nian-Yu,Zou, Kun,&Deng, Wei-Qiao.(2014).Efficient Fixation of CO2 by a Zinc-Coordinated Conjugated Microporous Polymer.CHEMSUSCHEM,7(8),2110-2114.
MLA Xie, Yong,et al."Efficient Fixation of CO2 by a Zinc-Coordinated Conjugated Microporous Polymer".CHEMSUSCHEM 7.8(2014):2110-2114.
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