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题名: Efficient Fixation of CO2 by a Zinc-Coordinated Conjugated Microporous Polymer
作者: Xie, Yong1, 2;  Wang, Ting-Ting2;  Yang, Rui-Xia2;  Huang, Nian-Yu1;  Zou, Kun1;  Deng, Wei-Qiao2
关键词: co(2) fixation ;  cyclic carbonates ;  heterogeneous catalysis ;  turnover frequencies ;  polymers
刊名: CHEMSUSCHEM
发表日期: 2014-08-01
DOI: 10.1002/cssc.201402162
卷: 7, 期:8, 页:2110-2114
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Multidisciplinary
研究领域[WOS]: Chemistry
英文摘要: Zinc-coordinated conjugated microporous polymers (Zn-CMPs), prepared by linking salen zinc and 1,3,5-triethynylbenzene, exhibit extraordinary activities (turnover frequencies of up to 11600 h(-1)), broad substrate scope, and group tolerance for the synthesis of functional organic carbonates by coupling epoxides with CO2 at 120 degrees C and 3.0 MPa without the use of additional solvents. The catalytic activity of Zn-CMP is comparable to those of homogeneous catalysts and superior to those of other heterogeneous catalysts. This catalyst could be reused more than ten times without a significant decrease in performance.
关键词[WOS]: CYCLIC CARBONATE SYNTHESIS ;  POROUS ORGANIC POLYMERS ;  HIGH-SURFACE-AREA ;  COUPLING REACTIONS ;  SALEN COMPLEXES ;  MILD CONDITIONS ;  IONIC LIQUIDS ;  EPOXIDES ;  DIOXIDE ;  CATALYST
语种: 英语
WOS记录号: WOS:000340519500007
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/145526
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.China Three Gorges Univ, Hubei Key Lab Nat Prod Res, Coll Chem & Life Sci, Yichang 443002, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China

Recommended Citation:
Xie, Yong,Wang, Ting-Ting,Yang, Rui-Xia,et al. Efficient Fixation of CO2 by a Zinc-Coordinated Conjugated Microporous Polymer[J]. CHEMSUSCHEM,2014,7(8):2110-2114.
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