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Rh catalysts supported on knitting aryl network polymers for the hydroformylation of higher olefins
Jiang, Miao1,3; Ding, Yunjie1,2; Yan, Li1; Song, Xiangen1; Lin, Ronghe1
KeywordTriphenylphosphine Knitting Aryl Network Polymer Rhodium Heterogeneous Catalyst HydrOformylation Of Higher Olefins
Source PublicationCHINESE JOURNAL OF CATALYSIS
2014-09-01
DOI10.1016/S1872-2067(14)600684
Volume35Issue:9Pages:1456-1464
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences ; Technology
WOS SubjectChemistry, Applied ; Chemistry, Physical ; Engineering, Chemical
WOS Research AreaChemistry ; Engineering
WOS KeywordMODIFIED RH/SIO2 CATALYST ; CARBON-DIOXIDE CAPTURE ; HETEROGENEOUS CATALYSTS ; MICROPOROUS POLYMERS ; MESOPOROUS SILICA ; ORGANIC FRAMEWORK ; NANOPARTICLES ; WATER ; HYDROGENATION ; PROPYLENE
AbstractRh catalysts supported on knitting aryl network polymers (Rh/KAPs) were prepared for the hydroformylation of higher olefins. Rh catalysts supported on triphenylphosphine-benzene-base polymers (Rh/KAPs-1) showed higher activity for the higher olefins than Rh/SiO2 catalysts. Fourier transform infrared spectroscopy, thermogravimetry, N-2 adsorption-desorption, X-ray diffraction, transmission electron microscopy, C-13 NMR, and P-31 NMR showed that the Rh/ICAPs-1 catalysts have high thermal stability, high surface area, hierarchical porosity, highly dispersed Rh nanoparticles, and in situ formed homogeneous active species during the reaction. (C) 2014, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.
Language英语
WOS IDWOS:000341070700005
Citation statistics
Cited Times:8[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/145566
Collection中国科学院大连化学物理研究所
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Liaoning, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Jiang, Miao,Ding, Yunjie,Yan, Li,et al. Rh catalysts supported on knitting aryl network polymers for the hydroformylation of higher olefins[J]. CHINESE JOURNAL OF CATALYSIS,2014,35(9):1456-1464.
APA Jiang, Miao,Ding, Yunjie,Yan, Li,Song, Xiangen,&Lin, Ronghe.(2014).Rh catalysts supported on knitting aryl network polymers for the hydroformylation of higher olefins.CHINESE JOURNAL OF CATALYSIS,35(9),1456-1464.
MLA Jiang, Miao,et al."Rh catalysts supported on knitting aryl network polymers for the hydroformylation of higher olefins".CHINESE JOURNAL OF CATALYSIS 35.9(2014):1456-1464.
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