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Rh catalysts supported on knitting aryl network polymers for the hydroformylation of higher olefins
Jiang, Miao1,3; Ding, Yunjie1,2; Yan, Li1; Song, Xiangen1; Lin, Ronghe1
关键词Triphenylphosphine Knitting Aryl Network Polymer Rhodium Heterogeneous Catalyst HydrOformylation Of Higher Olefins
刊名CHINESE JOURNAL OF CATALYSIS
2014-09-01
DOI10.1016/S1872-2067(14)600684
35期:9页:1456-1464
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences ; Technology
类目[WOS]Chemistry, Applied ; Chemistry, Physical ; Engineering, Chemical
研究领域[WOS]Chemistry ; Engineering
关键词[WOS]MODIFIED RH/SIO2 CATALYST ; CARBON-DIOXIDE CAPTURE ; HETEROGENEOUS CATALYSTS ; MICROPOROUS POLYMERS ; MESOPOROUS SILICA ; ORGANIC FRAMEWORK ; NANOPARTICLES ; WATER ; HYDROGENATION ; PROPYLENE
英文摘要Rh catalysts supported on knitting aryl network polymers (Rh/KAPs) were prepared for the hydroformylation of higher olefins. Rh catalysts supported on triphenylphosphine-benzene-base polymers (Rh/KAPs-1) showed higher activity for the higher olefins than Rh/SiO2 catalysts. Fourier transform infrared spectroscopy, thermogravimetry, N-2 adsorption-desorption, X-ray diffraction, transmission electron microscopy, C-13 NMR, and P-31 NMR showed that the Rh/ICAPs-1 catalysts have high thermal stability, high surface area, hierarchical porosity, highly dispersed Rh nanoparticles, and in situ formed homogeneous active species during the reaction. (C) 2014, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.
语种英语
WOS记录号WOS:000341070700005
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被引频次:8[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/145566
专题中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Liaoning, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
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Jiang, Miao,Ding, Yunjie,Yan, Li,et al. Rh catalysts supported on knitting aryl network polymers for the hydroformylation of higher olefins[J]. CHINESE JOURNAL OF CATALYSIS,2014,35(9):1456-1464.
APA Jiang, Miao,Ding, Yunjie,Yan, Li,Song, Xiangen,&Lin, Ronghe.(2014).Rh catalysts supported on knitting aryl network polymers for the hydroformylation of higher olefins.CHINESE JOURNAL OF CATALYSIS,35(9),1456-1464.
MLA Jiang, Miao,et al."Rh catalysts supported on knitting aryl network polymers for the hydroformylation of higher olefins".CHINESE JOURNAL OF CATALYSIS 35.9(2014):1456-1464.
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