DICP OpenIR
Effective thermodynamic alteration to Mg(NH2)(2)-LiH system: achieving near ambient-temperature hydrogen storage
Cao, Hujun1,2,3; Wu, Guotao1; Zhang, Yao4; Xiong, Zhitao1; Qiu, Jieshan2; Chen, Ping1
Source PublicationJOURNAL OF MATERIALS CHEMISTRY A
2014
DOI10.1039/c4ta03505d
Volume2Issue:38Pages:15816-15822
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences ; Technology
WOS SubjectChemistry, Physical ; Energy & Fuels ; Materials Science, Multidisciplinary
WOS Research AreaChemistry ; Energy & Fuels ; Materials Science
WOS KeywordMG-N-H ; COMPLEX HYDRIDES ; AMIDE-HALIDE ; LI4BN3H10 ; IMIDES ; LIBH4 ; LIH ; LINH2-MGH2 ; RELEASE ; LI3N
AbstractA strategy for thermodynamic improvement of 2Mg(NH2)(2)-3LiH composite via "stabilizing" the dehydrogenated product LiNH2 was developed. By introducing LiI, LiBr and LiBH4 to the composite, hydrogen release at 0.1 MPa equilibrium pressure is thermodynamically allowed at 333, 320 and 337 K, respectively, which are ten degree Celsius lower than the pristine composite. Moreover, the dehydrogenation kinetics and reversibility are significantly improved.
Language英语
WOS IDWOS:000342079200020
Citation statistics
Cited Times:23[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/145579
Collection中国科学院大连化学物理研究所
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China
2.Dalian Univ Technol, Carbon Res Lab, Liaoning Key Lab Energy Mat & Chem Engn, State Key Lab Fine Chem, Dalian 116024, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
4.Southeast Univ, Sch Mat Sci & Engn, Nanjing 211189, Jiangsu, Peoples R China
Recommended Citation
GB/T 7714
Cao, Hujun,Wu, Guotao,Zhang, Yao,et al. Effective thermodynamic alteration to Mg(NH2)(2)-LiH system: achieving near ambient-temperature hydrogen storage[J]. JOURNAL OF MATERIALS CHEMISTRY A,2014,2(38):15816-15822.
APA Cao, Hujun,Wu, Guotao,Zhang, Yao,Xiong, Zhitao,Qiu, Jieshan,&Chen, Ping.(2014).Effective thermodynamic alteration to Mg(NH2)(2)-LiH system: achieving near ambient-temperature hydrogen storage.JOURNAL OF MATERIALS CHEMISTRY A,2(38),15816-15822.
MLA Cao, Hujun,et al."Effective thermodynamic alteration to Mg(NH2)(2)-LiH system: achieving near ambient-temperature hydrogen storage".JOURNAL OF MATERIALS CHEMISTRY A 2.38(2014):15816-15822.
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