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题名: Rhodium(III)-catalyzed C-H alkynylation of azomethine ylides under mild conditions
作者: Zhang, Xueyun1, 2;  Qi, Zisong2;  Gao, Jian1;  Li, Xingwei2
刊名: ORGANIC & BIOMOLECULAR CHEMISTRY
发表日期: 2014
DOI: 10.1039/c4ob01596g
卷: 12, 期:46, 页:9329-9332
收录类别: SCI ;  IC
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: Rh(III)-catalyzed efficient C-H alkynylation of azomethine imines with alkynylated hypervalent iodine is developed under mild conditions. A broad scope of azomethine imines and alkyne substrates is established. The azomethine acts as a masked aldehyde and circumvents its poor directing effect.
关键词[WOS]: CATALYZED DIRECT ALKYNYLATION ;  BOND ACTIVATION ;  TERMINAL ALKYNES ;  ROOM-TEMPERATURE ;  GOLD ;  FUNCTIONALIZATION ;  HETEROCYCLES ;  CASCADE ;  2-ALKYNYLBENZALDEHYDE ;  ISOQUINOLINES
语种: 英语
WOS记录号: WOS:000344989700005
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/145624
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Qilu Univ Technol, Sch Chem & Pharmaceut Engn, Jinan 250353, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

Recommended Citation:
Zhang, Xueyun,Qi, Zisong,Gao, Jian,et al. Rhodium(III)-catalyzed C-H alkynylation of azomethine ylides under mild conditions[J]. ORGANIC & BIOMOLECULAR CHEMISTRY,2014,12(46):9329-9332.
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