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题名: tert-Butyl hydroperoxide (TBHP)-mediated oxidative self-coupling of amines to imines over a alpha-MnO2 catalyst
作者: Zhang, Zhe1, 2;  Wang, Feng1;  Wang, Min1;  Xu, Shutao1;  Chen, Haijun1, 2;  Zhang, Chaofeng1, 2;  Xu, Jie1
刊名: GREEN CHEMISTRY
发表日期: 2014
DOI: 10.1039/c3gc42312c
卷: 16, 期:5, 页:2523-2527
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Multidisciplinary
研究领域[WOS]: Chemistry
英文摘要: We here demonstrate a simple, efficient and eco-friendly protocol for the direct synthesis of imines from amines via a facile a-MnO2 catalyzed-procedure at rt. Up to 13 benzylic, heterocyclic, and normal aliphatic imines were synthesized with 95-99% selectivity at 82-99% conversion.
关键词[WOS]: AEROBIC OXIDATION ;  EFFICIENT CATALYST ;  SECONDARY-AMINES ;  GOLD CATALYSTS ;  OXIDE ;  DEHYDROGENATION ;  BENZYLAMINES ;  SYSTEM
语种: 英语
WOS记录号: WOS:000335005200022
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/145628
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China

Recommended Citation:
Zhang, Zhe,Wang, Feng,Wang, Min,et al. tert-Butyl hydroperoxide (TBHP)-mediated oxidative self-coupling of amines to imines over a alpha-MnO2 catalyst[J]. GREEN CHEMISTRY,2014,16(5):2523-2527.
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