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题名: Aerobic oxidative transformation of primary alcohols and amines to amides promoted by a hydroxyapatite-supported gold catalyst in water
作者: Wang, Wentao1;  Cong, Yu1;  Zhang, Leilei1;  Huang, Yanqiang1;  Wang, Xiaodong1;  Zhang, Tao1
关键词: Heterogeneous catalyst ;  Gold ;  Amides ;  Aerobic oxidation
刊名: TETRAHEDRON LETTERS
发表日期: 2014
DOI: 10.1016/j.tetlet.2013.10.133
卷: 55, 期:1, 页:124-127
收录类别: SCI ;  CCR
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: In the presence of an easily prepared hydroxyapatite-supported gold catalyst, namely Au/HAP, various kinds of structurally diverse primary alcohols including benzylic and aliphatic ones, and amines involving aromatic and secondary ones could be converted into the corresponding amides in water with up to 99% yield. Meanwhile, on the basis of experimental observations and literatures, a plausible reaction pathway was described to elucidate the reaction mechanism. (C) 2013 Elsevier Ltd. All rights reserved.
关键词[WOS]: SELECTIVE OXIDATION ;  BOND FORMATION ;  NANOPARTICLES ;  HYDROGENATION ;  OXYGEN ;  SIZE ;  MECHANISM ;  METHANOL ;  ETHANOL ;  ORIGIN
语种: 英语
WOS记录号: WOS:000329960500026
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/145638
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China

Recommended Citation:
Wang, Wentao,Cong, Yu,Zhang, Leilei,et al. Aerobic oxidative transformation of primary alcohols and amines to amides promoted by a hydroxyapatite-supported gold catalyst in water[J]. TETRAHEDRON LETTERS,2014,55(1):124-127.
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