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Synthesis of Fluorinated Heteroaromatics through Formal Substitution of a Nitro Group by Fluorine under Transition-Metal-Free Conditions
Guo, Ran-Ning1,2; Cai, Xian-Feng1; Shi, Lei1; Chen, Zhang-Pei1; Zhou, Yong-Gui1
KeywordFluorination Heterocycles Hydrogenation Nitro Compounds Rearomatization
Source PublicationCHEMISTRY-A EUROPEAN JOURNAL
2014-07-01
DOI10.1002/chem.201402282
Volume20Issue:27Pages:8343-8346
Indexed BySCI ; IC ; CCR
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Multidisciplinary
WOS Research AreaChemistry
WOS KeywordCOPPER-MEDIATED FLUORINATION ; ASYMMETRIC TRANSFER HYDROGENATION ; LATE-STAGE FLUORINATION ; C-H BONDS ; CATALYZED FLUORINATION ; MEDICINAL CHEMISTRY ; HANTZSCH ESTERS ; ARYL FLUORIDES ; F BOND ; PALLADIUM
AbstractAn efficient and transition-metal-free approach was developed to access a series of fluorinated heteroaromatics in moderate to excellent yields. This one-pot procedure features a triple-relay transformation of rapid dearomatization, fluorination, and rearomatization processes, which represents a conceptually novel strategy of combining partial hydrogenation and electrophilic fluorination.
Language英语
WOS IDWOS:000338019300018
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Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/145647
Collection中国科学院大连化学物理研究所
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Dalian Univ Technol, Dept Chem, Dalian 116012, Peoples R China
Recommended Citation
GB/T 7714
Guo, Ran-Ning,Cai, Xian-Feng,Shi, Lei,et al. Synthesis of Fluorinated Heteroaromatics through Formal Substitution of a Nitro Group by Fluorine under Transition-Metal-Free Conditions[J]. CHEMISTRY-A EUROPEAN JOURNAL,2014,20(27):8343-8346.
APA Guo, Ran-Ning,Cai, Xian-Feng,Shi, Lei,Chen, Zhang-Pei,&Zhou, Yong-Gui.(2014).Synthesis of Fluorinated Heteroaromatics through Formal Substitution of a Nitro Group by Fluorine under Transition-Metal-Free Conditions.CHEMISTRY-A EUROPEAN JOURNAL,20(27),8343-8346.
MLA Guo, Ran-Ning,et al."Synthesis of Fluorinated Heteroaromatics through Formal Substitution of a Nitro Group by Fluorine under Transition-Metal-Free Conditions".CHEMISTRY-A EUROPEAN JOURNAL 20.27(2014):8343-8346.
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