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题名: Synthesis of Fluorinated Heteroaromatics through Formal Substitution of a Nitro Group by Fluorine under Transition-Metal-Free Conditions
作者: Guo, Ran-Ning1, 2;  Cai, Xian-Feng1;  Shi, Lei1;  Chen, Zhang-Pei1;  Zhou, Yong-Gui1
关键词: fluorination ;  heterocycles ;  hydrogenation ;  nitro compounds ;  rearomatization
刊名: CHEMISTRY-A EUROPEAN JOURNAL
发表日期: 2014-07-01
DOI: 10.1002/chem.201402282
卷: 20, 期:27, 页:8343-8346
收录类别: SCI ;  IC ;  CCR
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Multidisciplinary
研究领域[WOS]: Chemistry
英文摘要: An efficient and transition-metal-free approach was developed to access a series of fluorinated heteroaromatics in moderate to excellent yields. This one-pot procedure features a triple-relay transformation of rapid dearomatization, fluorination, and rearomatization processes, which represents a conceptually novel strategy of combining partial hydrogenation and electrophilic fluorination.
关键词[WOS]: COPPER-MEDIATED FLUORINATION ;  ASYMMETRIC TRANSFER HYDROGENATION ;  LATE-STAGE FLUORINATION ;  C-H BONDS ;  CATALYZED FLUORINATION ;  MEDICINAL CHEMISTRY ;  HANTZSCH ESTERS ;  ARYL FLUORIDES ;  F BOND ;  PALLADIUM
语种: 英语
WOS记录号: WOS:000338019300018
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/145647
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Dalian Univ Technol, Dept Chem, Dalian 116012, Peoples R China

Recommended Citation:
Guo, Ran-Ning,Cai, Xian-Feng,Shi, Lei,et al. Synthesis of Fluorinated Heteroaromatics through Formal Substitution of a Nitro Group by Fluorine under Transition-Metal-Free Conditions[J]. CHEMISTRY-A EUROPEAN JOURNAL,2014,20(27):8343-8346.
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