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题名: Rh-ImiFerroPhos complexes catalyzed asymmetric hydrogenation of beta-substituted alpha,beta-unsaturated phosphonates
作者: Duan, Zhengchao1;  Wang, Lianzhi1;  Zuo, Xiaoyu1;  Hu, Xiangping2;  Zheng, Zhuo2
关键词: beta-Substituted alpha,beta-unsaturated phosphonate ;  Asymmetric catalytic hydrogenation ;  ImiFerroPhos ligands ;  Rhodium (II) complex ;  Chiral beta-substituted alkylphosphonate
刊名: CHINESE JOURNAL OF CATALYSIS
发表日期: 2014-02-01
DOI: 10.1016/S1872-2067(12)60742-6
卷: 35, 期:2, 页:227-231
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences ;  Technology
类目[WOS]: Chemistry, Applied ;  Chemistry, Physical ;  Engineering, Chemical
研究领域[WOS]: Chemistry ;  Engineering
英文摘要: A series of chiral ferrocenyl diphosphine ligands (ImiFerroPhos ligands) has been applied to the hydrogenation of beta-substituted alpha,beta-unsaturated phosphonates to generate a range of optically active beta-substituted alkylphosphonates in good yields with good enantioselectivity (up to 92% ee) under mild reaction conditions. (C) 2014, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.
关键词[WOS]: PHOTO-ARBUZOV REARRANGEMENTS ;  ENANTIOSELECTIVE HYDROGENATION ;  REACTIVE IMMUNIZATION ;  BENZYL PHOSPHITES ;  LIGANDS ;  PHOSPHORUS ;  STEREOCHEMISTRY ;  CARBANIONS ;  ANTIBODIES ;  NAPROXEN
语种: 英语
WOS记录号: WOS:000330555800009
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/145705
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Hubei Univ Nationalities, Sch Chem & Enviromental Engn, Enshi 445000, Hubei, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China

Recommended Citation:
Duan, Zhengchao,Wang, Lianzhi,Zuo, Xiaoyu,et al. Rh-ImiFerroPhos complexes catalyzed asymmetric hydrogenation of beta-substituted alpha,beta-unsaturated phosphonates[J]. CHINESE JOURNAL OF CATALYSIS,2014,35(2):227-231.
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