DICP OpenIR
The mechanism for production of abiogenic formate from CO2 and lactate from glycerine: uncatalyzed transfer hydrogenation of CO2 with glycerine under alkaline hydrothermal conditions
Shen, Zheng1,2; Gu, Minyan1; Zhang, Min1; Sang, Wenjing1; Zhou, Xuefei1; Zhang, Yalei1; Jin, Fangmin1
Source PublicationRSC ADVANCES
2014
DOI10.1039/c4ra00777h
Volume4Issue:29Pages:15256-15263
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Multidisciplinary
WOS Research AreaChemistry
WOS KeywordHIGH-TEMPERATURE WATER ; CARBON-DIOXIDE ; FORMIC-ACID ; LACTIC-ACID ; SUPERCRITICAL WATER ; TRANSFER REDUCTION ; ORGANIC-COMPOUNDS ; VERLEY REDUCTION ; ACRYLIC-ACID ; CATALYSIS
AbstractRecently, formate of possible abiogenic origin has been reported from uncatalyzed transfer hydrogenation of CO2 with glycerine under alkaline hydrothermal conditions. However, little is known about the mechanism for production of abiogenic formate from CO2 and lactate from glycerine during such processes. Herein, we investigated the formation of abiogenic formate from CO2, D2O solvent effect, reactor materials effect and H2O molecule catalysis for uncatalyzed transfer hydrogenation of CO2 with glycerine under alkaline hydrothermal conditions, and then have proposed and proved the potential reaction mechanism. The present work should help facilitate studies on industrial applications of CO2 reduction using abundant alcohol compounds as reducing materials rather than hydrogen, and the development of renewable high-valued chemicals from alternative biomass derivatives and the primary greenhouse gas to fossil fuel.
Language英语
WOS IDWOS:000333528900060
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/145718
Collection中国科学院大连化学物理研究所
Affiliation1.Tongji Univ, Natl Engn Res Ctr Facil Agr, State Key Lab Pollut Control & Resources Reuse, Key Lab Yangtze River Water Environm,MOE, Shanghai 200092, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Shen, Zheng,Gu, Minyan,Zhang, Min,et al. The mechanism for production of abiogenic formate from CO2 and lactate from glycerine: uncatalyzed transfer hydrogenation of CO2 with glycerine under alkaline hydrothermal conditions[J]. RSC ADVANCES,2014,4(29):15256-15263.
APA Shen, Zheng.,Gu, Minyan.,Zhang, Min.,Sang, Wenjing.,Zhou, Xuefei.,...&Jin, Fangmin.(2014).The mechanism for production of abiogenic formate from CO2 and lactate from glycerine: uncatalyzed transfer hydrogenation of CO2 with glycerine under alkaline hydrothermal conditions.RSC ADVANCES,4(29),15256-15263.
MLA Shen, Zheng,et al."The mechanism for production of abiogenic formate from CO2 and lactate from glycerine: uncatalyzed transfer hydrogenation of CO2 with glycerine under alkaline hydrothermal conditions".RSC ADVANCES 4.29(2014):15256-15263.
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