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The mechanism for production of abiogenic formate from CO2 and lactate from glycerine: uncatalyzed transfer hydrogenation of CO2 with glycerine under alkaline hydrothermal conditions
Shen, Zheng1,2; Gu, Minyan1; Zhang, Min1; Sang, Wenjing1; Zhou, Xuefei1; Zhang, Yalei1; Jin, Fangmin1
刊名RSC ADVANCES
2014
DOI10.1039/c4ra00777h
4期:29页:15256-15263
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Multidisciplinary
研究领域[WOS]Chemistry
关键词[WOS]HIGH-TEMPERATURE WATER ; CARBON-DIOXIDE ; FORMIC-ACID ; LACTIC-ACID ; SUPERCRITICAL WATER ; TRANSFER REDUCTION ; ORGANIC-COMPOUNDS ; VERLEY REDUCTION ; ACRYLIC-ACID ; CATALYSIS
英文摘要Recently, formate of possible abiogenic origin has been reported from uncatalyzed transfer hydrogenation of CO2 with glycerine under alkaline hydrothermal conditions. However, little is known about the mechanism for production of abiogenic formate from CO2 and lactate from glycerine during such processes. Herein, we investigated the formation of abiogenic formate from CO2, D2O solvent effect, reactor materials effect and H2O molecule catalysis for uncatalyzed transfer hydrogenation of CO2 with glycerine under alkaline hydrothermal conditions, and then have proposed and proved the potential reaction mechanism. The present work should help facilitate studies on industrial applications of CO2 reduction using abundant alcohol compounds as reducing materials rather than hydrogen, and the development of renewable high-valued chemicals from alternative biomass derivatives and the primary greenhouse gas to fossil fuel.
语种英语
WOS记录号WOS:000333528900060
引用统计
被引频次:5[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/145718
专题中国科学院大连化学物理研究所
作者单位1.Tongji Univ, Natl Engn Res Ctr Facil Agr, State Key Lab Pollut Control & Resources Reuse, Key Lab Yangtze River Water Environm,MOE, Shanghai 200092, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
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GB/T 7714
Shen, Zheng,Gu, Minyan,Zhang, Min,et al. The mechanism for production of abiogenic formate from CO2 and lactate from glycerine: uncatalyzed transfer hydrogenation of CO2 with glycerine under alkaline hydrothermal conditions[J]. RSC ADVANCES,2014,4(29):15256-15263.
APA Shen, Zheng.,Gu, Minyan.,Zhang, Min.,Sang, Wenjing.,Zhou, Xuefei.,...&Jin, Fangmin.(2014).The mechanism for production of abiogenic formate from CO2 and lactate from glycerine: uncatalyzed transfer hydrogenation of CO2 with glycerine under alkaline hydrothermal conditions.RSC ADVANCES,4(29),15256-15263.
MLA Shen, Zheng,et al."The mechanism for production of abiogenic formate from CO2 and lactate from glycerine: uncatalyzed transfer hydrogenation of CO2 with glycerine under alkaline hydrothermal conditions".RSC ADVANCES 4.29(2014):15256-15263.
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