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题名: The mechanism for production of abiogenic formate from CO2 and lactate from glycerine: uncatalyzed transfer hydrogenation of CO2 with glycerine under alkaline hydrothermal conditions
作者: Shen, Zheng1, 2;  Gu, Minyan1;  Zhang, Min1;  Sang, Wenjing1;  Zhou, Xuefei1;  Zhang, Yalei1;  Jin, Fangmin1
刊名: RSC ADVANCES
发表日期: 2014
DOI: 10.1039/c4ra00777h
卷: 4, 期:29, 页:15256-15263
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Multidisciplinary
研究领域[WOS]: Chemistry
英文摘要: Recently, formate of possible abiogenic origin has been reported from uncatalyzed transfer hydrogenation of CO2 with glycerine under alkaline hydrothermal conditions. However, little is known about the mechanism for production of abiogenic formate from CO2 and lactate from glycerine during such processes. Herein, we investigated the formation of abiogenic formate from CO2, D2O solvent effect, reactor materials effect and H2O molecule catalysis for uncatalyzed transfer hydrogenation of CO2 with glycerine under alkaline hydrothermal conditions, and then have proposed and proved the potential reaction mechanism. The present work should help facilitate studies on industrial applications of CO2 reduction using abundant alcohol compounds as reducing materials rather than hydrogen, and the development of renewable high-valued chemicals from alternative biomass derivatives and the primary greenhouse gas to fossil fuel.
关键词[WOS]: HIGH-TEMPERATURE WATER ;  CARBON-DIOXIDE ;  FORMIC-ACID ;  LACTIC-ACID ;  SUPERCRITICAL WATER ;  TRANSFER REDUCTION ;  ORGANIC-COMPOUNDS ;  VERLEY REDUCTION ;  ACRYLIC-ACID ;  CATALYSIS
语种: 英语
WOS记录号: WOS:000333528900060
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/145718
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Tongji Univ, Natl Engn Res Ctr Facil Agr, State Key Lab Pollut Control & Resources Reuse, Key Lab Yangtze River Water Environm,MOE, Shanghai 200092, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China

Recommended Citation:
Shen, Zheng,Gu, Minyan,Zhang, Min,et al. The mechanism for production of abiogenic formate from CO2 and lactate from glycerine: uncatalyzed transfer hydrogenation of CO2 with glycerine under alkaline hydrothermal conditions[J]. RSC ADVANCES,2014,4(29):15256-15263.
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