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Vibrationally Resolved Photoelectron Imaging of Au3H-
Liu, Zhiling; Qin, Zhengbo; Wu, Xia; Xie, Hua; Cong, Ran; Tang, Zichao
刊名JOURNAL OF PHYSICAL CHEMISTRY A
2014-02-13
DOI10.1021/jp411639r
118期:6页:1031-1037
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Physical ; Physics, Atomic, Molecular & Chemical
研究领域[WOS]Chemistry ; Physics
关键词[WOS]MATRIX INFRARED-SPECTRA ; TRANSFORM EMISSION-SPECTROSCOPY ; COINAGE METAL-HYDRIDES ; DFT CALCULATIONS ; GOLD CLUSTERS ; THEORETICAL CHEMISTRY ; SOLID HYDROGEN ; MP2 ENERGY ; BASIS-SETS ; MH4-M
英文摘要We report a combined photoelectron velocity map imaging spectroscopy and density functional theory investigation on the Au3H- anion. Transition between the anionic electronic ground state and the neutral electronic ground state is revealed. Vibrationally resolved spectra were recorded at two different photon energies, providing a wealth of spectroscopic information for the electronic ground state of the Au3H. Franck-Condon simulations of the ground-state transition are carried out to assist in the assignment of the vibrationally resolved spectra. The electron affinity and vertical detachment energy of Au3H are measured to be 2.548 +/- 0.001 and 2.570 +/- 0.001 eV, respectively. Three stretching vibrational modes are determined to be activated upon photodetachment, with the frequencies of 2100 +/- 100, 177 +/- 10, and 96 +/- 10 cm(-1).
语种英语
WOS记录号WOS:000331493500009
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被引频次:2[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/145741
专题中国科学院大连化学物理研究所
作者单位Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China
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GB/T 7714
Liu, Zhiling,Qin, Zhengbo,Wu, Xia,et al. Vibrationally Resolved Photoelectron Imaging of Au3H-[J]. JOURNAL OF PHYSICAL CHEMISTRY A,2014,118(6):1031-1037.
APA Liu, Zhiling,Qin, Zhengbo,Wu, Xia,Xie, Hua,Cong, Ran,&Tang, Zichao.(2014).Vibrationally Resolved Photoelectron Imaging of Au3H-.JOURNAL OF PHYSICAL CHEMISTRY A,118(6),1031-1037.
MLA Liu, Zhiling,et al."Vibrationally Resolved Photoelectron Imaging of Au3H-".JOURNAL OF PHYSICAL CHEMISTRY A 118.6(2014):1031-1037.
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