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题名: Direct Synthesis of Phenol from Benzene by Pd - VOx Nanoparticles Using Molecular Oxygen
作者: Shang, Sensen1, 2;  Yang, Hua1, 2;  Li, Jun1;  Chen, Bo1, 2;  Lv, Ying1;  Gao, Shuang1
关键词: benzene ;  hydroxylation ;  nanoparticles ;  phenol ;  synthetic methods
刊名: CHEMPLUSCHEM
发表日期: 2014-05-01
DOI: 10.1002/cplu.201400007
卷: 79, 期:5, 页:680-683
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Multidisciplinary
研究领域[WOS]: Chemistry
英文摘要: Novel PdVOx nanoparticles (NPs) prepared by a one-pot hydrogenation method are reported. X-ray diffraction, X-ray photoelectron spectroscopy, transmission electron microscopy, and UV/Vis spectroscopy were performed to characterize the PdVOx NPs. The NPs catalyzed benzene directly to phenol in 5.2% yield with more than 99% selectivity using O-2 as the sole oxidant.
关键词[WOS]: ONE-STEP HYDROXYLATION ;  SOLVENT-FREE OXIDATION ;  CARBON-HYDROGEN BONDS ;  CATALYTIC-OXIDATION ;  NITROUS-OXIDE ;  ACTIVATION ;  PEROXIDE ;  ARYLATION ;  AROMATICS ;  ALDEHYDES
语种: 英语
WOS记录号: WOS:000335515800006
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/145751
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, Beijing 10049, Peoples R China

Recommended Citation:
Shang, Sensen,Yang, Hua,Li, Jun,et al. Direct Synthesis of Phenol from Benzene by Pd - VOx Nanoparticles Using Molecular Oxygen[J]. CHEMPLUSCHEM,2014,79(5):680-683.
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