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Palladium-Catalyzed Oxidative Heck-Type Allylation of beta,beta-Disubstituted Enones with Allyl Carbonates
Jin, Weiwei1; Yang, Qin1; Wu, Ping1; Chen, Jiping1; Yu, Zhengkun1,2
关键词Allyl Carbonates Allylation C-h Activation Enones Ketene Dithioacetals Palladium
刊名ADVANCED SYNTHESIS & CATALYSIS
2014-06-16
DOI10.1002/adsc.201400076
356期:9页:2097-2102
收录类别SCI ; IC
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Applied ; Chemistry, Organic
研究领域[WOS]Chemistry
关键词[WOS]OXO KETENE DITHIOACETALS ; H BOND ACTIVATION ; EFFICIENT SYNTHESIS ; SIMPLE ALKENES ; VINYL KETONES ; OLEFINATION ; HETEROARENES ; DERIVATIVES ; ZOANTHENOL ; MECHANISM
英文摘要The palladium-catalyzed oxidative Heck-type allylation of beta,beta-disubstitutedenones, i.e., alpha-oxoketene dithioacetals, was efficiently realized with allyl carbonates, providing a concise route to highly functionalized dienes. The present synthetic methodology utilizes the substrate activation strategy to activate the C-H bond of beta,beta-disubstituted enones by introduction of a 1,2-dithiolane functionality to make the enone substrate highly polarized and thus increase its reactivity, demonstrating rare examples for transition metal-catalyzed allylic substitution of beta,beta-disubstituted enones through a Heck-type allylation process.
语种英语
WOS记录号WOS:000337609400020
引用统计
被引频次:12[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/145763
专题中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China
2.Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
推荐引用方式
GB/T 7714
Jin, Weiwei,Yang, Qin,Wu, Ping,et al. Palladium-Catalyzed Oxidative Heck-Type Allylation of beta,beta-Disubstituted Enones with Allyl Carbonates[J]. ADVANCED SYNTHESIS & CATALYSIS,2014,356(9):2097-2102.
APA Jin, Weiwei,Yang, Qin,Wu, Ping,Chen, Jiping,&Yu, Zhengkun.(2014).Palladium-Catalyzed Oxidative Heck-Type Allylation of beta,beta-Disubstituted Enones with Allyl Carbonates.ADVANCED SYNTHESIS & CATALYSIS,356(9),2097-2102.
MLA Jin, Weiwei,et al."Palladium-Catalyzed Oxidative Heck-Type Allylation of beta,beta-Disubstituted Enones with Allyl Carbonates".ADVANCED SYNTHESIS & CATALYSIS 356.9(2014):2097-2102.
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