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题名: Highly Enantioselective Copper-Catalyzed Propargylic Substitution of Propargylic Acetates with 1,3-Dicarbonyl Compounds
作者: Han, Fu-Zhong1, 2;  Zhu, Fu-Lin2;  Wang, Ya-Hui2;  Zou, Yuan2;  Hu, Xin-Hu2;  Chen, Song2;  Hu, Xiang-Ping2
刊名: ORGANIC LETTERS
发表日期: 2014-01-17
DOI: 10.1021/ol403469m
卷: 16, 期:2, 页:588-591
收录类别: SCI ;  IC ;  CCR
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: A chiral tridentate ketimine P,N,N-ligand has been successfully applied in the copper-catalyzed enantioselective propargylic substitution of propargylic acetates with a variety of beta-dicarbonyl compounds, in which excellent enantioselectivities (up to >99% ee) and high yields have been obtained.
关键词[WOS]: ALLYLIC ALKYLATIONS ;  ALCOHOLS ;  AMINATION ;  AMINES ;  ESTERS ;  ORGANOCATALYSTS ;  DERIVATIVES ;  COMPLEXES ;  ALDEHYDES ;  LIGANDS
语种: 英语
WOS记录号: WOS:000330098400067
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/145768
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Qiqihar Univ, Coll Chem & Chem Engn, Qiqihar 161006, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

Recommended Citation:
Han, Fu-Zhong,Zhu, Fu-Lin,Wang, Ya-Hui,et al. Highly Enantioselective Copper-Catalyzed Propargylic Substitution of Propargylic Acetates with 1,3-Dicarbonyl Compounds[J]. ORGANIC LETTERS,2014,16(2):588-591.
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