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题名: Rhodium(III)-Catalyzed Redox-Neutral C-H Arylation via Rearomatization
作者: Zhang, Xueyun1, 2;  Wang, Fen1;  Qi, Zisong1;  Yu, Songjie1;  Li, Xingwei1
刊名: ORGANIC LETTERS
发表日期: 2014-03-21
DOI: 10.1021/ol500186j
卷: 16, 期:6, 页:1586-1589
收录类别: SCI ;  IC ;  CCR
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: Rhodium(III)-catalyzed arylation of arenes bearing a chelating group has been realized via a redox-economy process using 4-hydroxycyclohexa-2,5-dienones as the arylating reagents, leading to the synthesis of 3-arylated phenols. This redox-neutral process proceeds via a C-H activation pathway with rearomatization being the driving force.
关键词[WOS]: BOND ACTIVATION ;  MILD CONDITIONS ;  CATALYZED ANNULATION ;  CONJUGATE ADDITION ;  DIRECTING GROUPS ;  FACILE SYNTHESIS ;  BORONIC ACIDS ;  EASY ROUTE ;  RHODIUM ;  ARENES
语种: 英语
WOS记录号: WOS:000333477400013
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/145799
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Qilu Univ Technol, Sch Chem & Pharmaceutial Engn, Jinan 250353, Peoples R China

Recommended Citation:
Zhang, Xueyun,Wang, Fen,Qi, Zisong,et al. Rhodium(III)-Catalyzed Redox-Neutral C-H Arylation via Rearomatization[J]. ORGANIC LETTERS,2014,16(6):1586-1589.
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