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题名: A Streamlined Synthesis of 2,3-Dihydrobenzofurans via the ortho-Quinone Methides Generated from 2-Alkyl-Substituted Phenols
作者: Wu, Bo1;  Chen, Mu-Wang1;  Ye, Zhi-Shi1;  Yu, Chang-Bin1;  Zhou, Yong-Gui1
关键词: 2 ;  3-dihydrobenzofurans ;  ortho-quinone methides ;  synthesis
刊名: ADVANCED SYNTHESIS & CATALYSIS
发表日期: 2014-02-10
DOI: 10.1002/adsc.201300830
卷: 356, 期:2-3, 页:383-387
收录类别: SCI ;  IC ;  CCR
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Applied ;  Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: A facile method for the stereoselective synthesis of trans-2,3-dihydrobenzofurans from ortho-quinone methides in situ generated from readily available 2-alkyl-substituted phenols using silver oxide-mediated oxidation has been developed. Additionally, the 2,3-dihydrobenzofurans can be further transformed into the aromatized 2,3-disubstituted benzofurans in the presence of DDQ.
关键词[WOS]: ANTHRACYCLINE ANTITUMOR ANTIBIOTICS ;  ENANTIOSELECTIVE SYNTHESIS ;  RADICAL CYCLIZATION ;  2,3-DISUBSTITUTED DIHYDROBENZOFURANS ;  DIASTEREOSELECTIVE SYNTHESIS ;  ASYMMETRIC-SYNTHESIS ;  OXIDATION REACTIONS ;  RAPID SYNTHESIS ;  ONE-POT ;  ACID
语种: 英语
WOS记录号: WOS:000332000200017
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/145810
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China

Recommended Citation:
Wu, Bo,Chen, Mu-Wang,Ye, Zhi-Shi,et al. A Streamlined Synthesis of 2,3-Dihydrobenzofurans via the ortho-Quinone Methides Generated from 2-Alkyl-Substituted Phenols[J]. ADVANCED SYNTHESIS & CATALYSIS,2014,356(2-3):383-387.
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