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TG-FTIR, Py-two-dimensional GC-MS with heart-cutting and LC-MS/MS to reveal hydrocyanic acid formation mechanisms during glycine pyrolysis
Hao, Jufang1,2; Guo, Jizhao2; Ding, Li2; Xie, Fuwei2; Xia, Qiaoling2; Xie, Jianping2
关键词Glycine Pyrolysis Hydrocyanic Acid Formation Mechanism
刊名JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
2014
DOI10.1007/s10973-013-3214-0
115期:1页:667-673
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Analytical ; Chemistry, Physical
研究领域[WOS]Chemistry
关键词[WOS]ALPHA-AMINO-ACIDS ; MASS-SPECTROMETRY ; THERMAL-DECOMPOSITION ; SOLID-STATE ; PRODUCTS ; LEUCINE
英文摘要To elucidate the formation process of HCN from the pyrolysis of glycine, the small molecule gaseous pyrolysates, H2O, NH3, CO2, CO, HNCO, and HCN, were analyzed in real-time by TG-FTIR. The appearance of the volatile pyrolysis products and the solid residue was determined in real-time at their corresponding formation temperatures by online Py-two-dimensional GC-MS with heart-cutting and LC-MS/MS. The pyrolysis of 2,5-diketopiperazine, a thermolytic by-product of glycine pyrolysis, was also studied. The results showed that: (1) the pyrolysis of glycine can be divided into three temperature ranges 200-300, 300-440, and 440-900 A degrees C; HCN forms in each range with three peaks appearing at 273, 422, and 763 A degrees C, respectively. (2) The mechanistic pathways of HCN formation from glycine in the low- and high-temperature heating stages are different. Below 273 A degrees C, glycine undergoes a decarboxylation reaction to produce methylamine, which subsequently forms HCN by means of dehydrogenation. Above 300 A degrees C, glycine gives relatively large amounts of HCN via 2,5-diketopiperazine and subsequent HNCO or methylenimine formation.
语种英语
WOS记录号WOS:000329621100081
引用统计
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/145817
专题中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.CNTC, Zhengzhou Tobacco Res Inst, Zhengzhou 450001, Henan, Peoples R China
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GB/T 7714
Hao, Jufang,Guo, Jizhao,Ding, Li,et al. TG-FTIR, Py-two-dimensional GC-MS with heart-cutting and LC-MS/MS to reveal hydrocyanic acid formation mechanisms during glycine pyrolysis[J]. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY,2014,115(1):667-673.
APA Hao, Jufang,Guo, Jizhao,Ding, Li,Xie, Fuwei,Xia, Qiaoling,&Xie, Jianping.(2014).TG-FTIR, Py-two-dimensional GC-MS with heart-cutting and LC-MS/MS to reveal hydrocyanic acid formation mechanisms during glycine pyrolysis.JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY,115(1),667-673.
MLA Hao, Jufang,et al."TG-FTIR, Py-two-dimensional GC-MS with heart-cutting and LC-MS/MS to reveal hydrocyanic acid formation mechanisms during glycine pyrolysis".JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY 115.1(2014):667-673.
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