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题名: 4,5-Dihydropyrrolo[1,2-a]quinoxalines: A Tunable and Regenerable Biomimetic Hydrogen Source
作者: Chen, Zhang-Pei1;  Chen, Mu-Wang1;  Guo, Ran-Ning1;  Zhou, Yong-Gui1
刊名: ORGANIC LETTERS
发表日期: 2014-03-07
DOI: 10.1021/ol500176v
卷: 16, 期:5, 页:1406-1409
收录类别: SCI ;  IC ;  CCR
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: A series of tunable and regenerable biomimetic hydrogen sources, 4,5-dihydropyrrolo[1,2-a]quinoxalines, have been synthesized and applied in biomimetic asymmetric hydrogenation of 3-aryl-2H-benzo[b][1,4]oxazines and 1-alkyl-3-aryl-quinoxalin-2(1H)-ones, providing the chiral amines with up to 92% and 89% ee, respectively.
关键词[WOS]: ASYMMETRIC TRANSFER HYDROGENATION ;  CHIRAL PHOSPHORIC-ACID ;  ORGANOCATALYTIC TRANSFER HYDROGENATION ;  ENANTIOSELECTIVE TRANSFER HYDROGENATION ;  CATALYZED TRANSFER HYDROGENATION ;  IN-SITU REGENERATION ;  HANTZSCH ESTERS ;  NAD(P)H MODEL ;  ALPHA,BETA-UNSATURATED ALDEHYDES ;  REDUCTIVE AMINATION
语种: 英语
WOS记录号: WOS:000332756400034
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/145842
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China

Recommended Citation:
Chen, Zhang-Pei,Chen, Mu-Wang,Guo, Ran-Ning,et al. 4,5-Dihydropyrrolo[1,2-a]quinoxalines: A Tunable and Regenerable Biomimetic Hydrogen Source[J]. ORGANIC LETTERS,2014,16(5):1406-1409.
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