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4,5-Dihydropyrrolo[1,2-a]quinoxalines: A Tunable and Regenerable Biomimetic Hydrogen Source
Chen, Zhang-Pei; Chen, Mu-Wang; Guo, Ran-Ning; Zhou, Yong-Gui
Source PublicationORGANIC LETTERS
2014-03-07
DOI10.1021/ol500176v
Volume16Issue:5Pages:1406-1409
Indexed BySCI ; IC ; CCR
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Organic
WOS Research AreaChemistry
WOS KeywordASYMMETRIC TRANSFER HYDROGENATION ; CHIRAL PHOSPHORIC-ACID ; ORGANOCATALYTIC TRANSFER HYDROGENATION ; ENANTIOSELECTIVE TRANSFER HYDROGENATION ; CATALYZED TRANSFER HYDROGENATION ; IN-SITU REGENERATION ; HANTZSCH ESTERS ; NAD(P)H MODEL ; ALPHA,BETA-UNSATURATED ALDEHYDES ; REDUCTIVE AMINATION
AbstractA series of tunable and regenerable biomimetic hydrogen sources, 4,5-dihydropyrrolo[1,2-a]quinoxalines, have been synthesized and applied in biomimetic asymmetric hydrogenation of 3-aryl-2H-benzo[b][1,4]oxazines and 1-alkyl-3-aryl-quinoxalin-2(1H)-ones, providing the chiral amines with up to 92% and 89% ee, respectively.
Language英语
WOS IDWOS:000332756400034
Citation statistics
Cited Times:30[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/145842
Collection中国科学院大连化学物理研究所
AffiliationChinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Chen, Zhang-Pei,Chen, Mu-Wang,Guo, Ran-Ning,et al. 4,5-Dihydropyrrolo[1,2-a]quinoxalines: A Tunable and Regenerable Biomimetic Hydrogen Source[J]. ORGANIC LETTERS,2014,16(5):1406-1409.
APA Chen, Zhang-Pei,Chen, Mu-Wang,Guo, Ran-Ning,&Zhou, Yong-Gui.(2014).4,5-Dihydropyrrolo[1,2-a]quinoxalines: A Tunable and Regenerable Biomimetic Hydrogen Source.ORGANIC LETTERS,16(5),1406-1409.
MLA Chen, Zhang-Pei,et al."4,5-Dihydropyrrolo[1,2-a]quinoxalines: A Tunable and Regenerable Biomimetic Hydrogen Source".ORGANIC LETTERS 16.5(2014):1406-1409.
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