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题名: Efficient aerobic oxidation of biomass-derived 5-hydroxymethylfurfural to 2,5-diformylfuran catalyzed by magnetic nanoparticle supported manganese oxide
作者: Liu, Bing1, 2;  Zhang, Zehui1, 2;  Lv, Kangle1, 2;  Deng, Kejian1, 2;  Duan, Hongmin3
关键词: Biomass ;  2,5-Diformylfuran ;  Aerobic oxidation ;  5-Hydroxymethylfurfural ;  Manganese oxide ;  Magnetic nanoparticles
刊名: APPLIED CATALYSIS A-GENERAL
发表日期: 2014-02-22
DOI: 10.1016/j.apcata.2013.12.014
卷: 472, 页:64-71
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences ;  Life Sciences & Biomedicine
类目[WOS]: Chemistry, Physical ;  Environmental Sciences
研究领域[WOS]: Chemistry ;  Environmental Sciences & Ecology
英文摘要: Magnetic Fe3O4 supported Mn3O4 nanoparticles (Fe3O4/Mn3O4) were prepared by the solvent thermal method, and its structure was characterized by XRD, XI'S, TEM, and FT-IR technologies. The resulting Fe3O4/Mn3O4 nanoparticles could be used as an excellent heterogeneous catalyst for the aerobic oxidation of the biomass-derived model molecule 5-hydroxymethylfurfural into 2,5-diformylfuran (DFF) under benign reaction conditions. Some important reaction parameters such as reaction temperature, catalyst amount, solvent, oxidant, and oxygen pressure were explored and high DFF yield of 82.1% with HMF conversion of 100% were obtained in DMF under optimal reaction conditions. More importantly, the catalyst could be readily separated from the reaction mixture by a permanent magnet, and recycled up to 6 times without the significant loss of its catalytic activity. (C) 2013 Elsevier B.V. All rights reserved.
关键词[WOS]: PULSED-LASER ABLATION ;  HETEROGENEOUS CATALYST ;  SELECTIVE OXIDATION ;  IONIC LIQUIDS ;  CONVERSION ;  ACID ;  DERIVATIVES ;  CELLULOSE ;  FRUCTOSE ;  HEMICELLULOSE
语种: 英语
WOS记录号: WOS:000333856200008
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/145875
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.South Cent Univ Nationalities, Dept Chem, Key Lab Catalysis & Mat Sci, State Ethn Affairs Commiss, Wuhan 430074, Peoples R China
2.South Cent Univ Nationalities, Minist Educ, Wuhan 430074, Peoples R China
3.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China

Recommended Citation:
Liu, Bing,Zhang, Zehui,Lv, Kangle,et al. Efficient aerobic oxidation of biomass-derived 5-hydroxymethylfurfural to 2,5-diformylfuran catalyzed by magnetic nanoparticle supported manganese oxide[J]. APPLIED CATALYSIS A-GENERAL,2014,472:64-71.
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