DICP OpenIR
State-to-state dynamics of the H*(n) plus HD -> D*(n ') + H-2 reactive scattering
Yu, Shengrui; Su, Shu; Dai, Dongxu; Yuan, Kaijun; Yang, Xueming
Source PublicationJOURNAL OF CHEMICAL PHYSICS
2014-01-21
DOI10.1063/1.4861759
Volume140Issue:3
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectPhysics, Atomic, Molecular & Chemical
WOS Research AreaPhysics
WOS KeywordPOTENTIAL-ENERGY SURFACES ; DIFFERENTIAL CROSS-SECTIONS ; REACTIVE SCATTERING ; H-3(+) ; HYDROGEN ; SYSTEM ; D+ ; H+ ; COLLISIONS ; ATOM
AbstractThe state-to-state dynamics of the H*(n) + HD -> D*(n') + H-2 reactive scattering at the collision energy of 0.5 eV have been carried out for the first time by using H-atom Rydberg tagging time-of-flight technique. Experimental results show that the angular distribution of the total H-2 products presents clearly forward-backward asymmetric, which considerably differs from that of the corresponding H+ + HD -> D+ + H-2 reaction predicted by previously theoretical calculations. Such disagreement between these two processes suggests that the Fermi independent-collider model is also not valid in describing the dynamics of isotopic variants of the H* + H-2 reaction. The rotational state distribution of the H-2 products demonstrates a saw-toothed distribution with odd-j' > even-j'. This interesting observation is strongly influenced by nuclear spin statistics. (C) 2014 AIP Publishing LLC.
Language英语
WOS IDWOS:000330614400028
Citation statistics
Cited Times:5[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/145877
Collection中国科学院大连化学物理研究所
AffiliationChinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Yu, Shengrui,Su, Shu,Dai, Dongxu,et al. State-to-state dynamics of the H*(n) plus HD -> D*(n ') + H-2 reactive scattering[J]. JOURNAL OF CHEMICAL PHYSICS,2014,140(3).
APA Yu, Shengrui,Su, Shu,Dai, Dongxu,Yuan, Kaijun,&Yang, Xueming.(2014).State-to-state dynamics of the H*(n) plus HD -> D*(n ') + H-2 reactive scattering.JOURNAL OF CHEMICAL PHYSICS,140(3).
MLA Yu, Shengrui,et al."State-to-state dynamics of the H*(n) plus HD -> D*(n ') + H-2 reactive scattering".JOURNAL OF CHEMICAL PHYSICS 140.3(2014).
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