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题名: Hydrogenation/Hydrolytic Ring Opening of 5-HMF by Cp*-Iridium(III) Half-Sandwich Complexes for Bioketones Synthesis
作者: Xu, Zhanwei1;  Yan, Peifang1;  Xu, Wenjuan1;  Liu, Xiumei1;  Xia, Zhi1;  Chung, Benjamin1;  Jia, Songyan1;  Zhang, Z. Conrad1
关键词: homogeneous catalysis ;  hydrogenation ;  iridium catalyst ;  5-HMF ;  ketones
刊名: ACS CATALYSIS
发表日期: 2015-02-01
DOI: 10.1021/cs501874v
卷: 5, 期:2, 页:788-792
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Physical
研究领域[WOS]: Chemistry
英文摘要: A new method for one-step synthesis of ketones from biobased 5-hydroxymethylfurfural (5-HMF) and its derivatives is reported. Bipyridine coordinated Cp*-Iridium(III) complexes (Cp*, 1,2,3,4,5-pentamethylcyclopenta-1,3-diene) exhibit highly efficient catalytic performance for hydrogenation/hydrolytic ring opening of 5-HMF and derivatives to produce ketones. The catalytic mechanism is proposed to proceed via carbonyl hydrogenation, hydroxyl group promoted and directed hydrolytic furan ring opening, followed by hydrogenation of a,fi-unsaturated carbonyl compound based on the experimental and independent events' statistical calculation results.
关键词[WOS]: CATALYTIC CONVERSION ;  RENEWABLE RESOURCES ;  IRIDIUM COMPLEXES ;  LEVULINIC ACID ;  BIOMASS ;  FRUCTOSE ;  HYDRODEOXYGENATION ;  HYDROGENOLYSIS ;  DECOMPOSITION ;  REDUCTION
语种: 英语
WOS记录号: WOS:000349275300034
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/145939
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, State Key Lab Catalysis, Dalian 116023, Peoples R China

Recommended Citation:
Xu, Zhanwei,Yan, Peifang,Xu, Wenjuan,et al. Hydrogenation/Hydrolytic Ring Opening of 5-HMF by Cp*-Iridium(III) Half-Sandwich Complexes for Bioketones Synthesis[J]. ACS CATALYSIS,2015,5(2):788-792.
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