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题名: Well-defined BiOCl colloidal ultrathin nanosheets: synthesis, characterization, and application in photocatalytic aerobic oxidation of secondary amines
作者: Wu, Yihui1;  Yuan, Bo1;  Li, Mingrun1;  Zhang, Wen-Hua1;  Liu, Yan1;  Li, Can1
刊名: CHEMICAL SCIENCE
发表日期: 2015
DOI: 10.1039/c4sc03229b
卷: 6, 期:3, 页:1873-1878
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Multidisciplinary
研究领域[WOS]: Chemistry
英文摘要: We demonstrate the first colloidal synthesis of single-crystalline BiOCl ultrathin nanosheets (UTNSs) that feature a well-defined square morphology. Unlike BiOCl nanomaterials prepared by hydrothermal routes, our colloidal BiOCl UTNSs exhibit hydrophobic surface properties and high activity and selectivity toward the photocatalytic aerobic oxidation of secondary amines to corresponding imines at room temperature. Hence, the application of BiOCl nanomaterials has been successfully extended from the widely studied photodecomposition of pollutants in aqueous solution to the synthesis of fine chemicals in organic solvent using a green approach.
关键词[WOS]: SINGLE-CRYSTALLINE NANOSHEETS ;  HIGHLY EFFICIENT ;  ELECTRONIC-STRUCTURE ;  NANOCRYSTALS SYNTHESIS ;  IMINE SYNTHESIS ;  PHASE ;  NANOSTRUCTURES ;  PROTOCOLS ;  LIGAND ;  SHAPE
语种: 英语
WOS记录号: WOS:000349832600031
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/145948
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Natl Lab Clean Energy, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China

Recommended Citation:
Wu, Yihui,Yuan, Bo,Li, Mingrun,et al. Well-defined BiOCl colloidal ultrathin nanosheets: synthesis, characterization, and application in photocatalytic aerobic oxidation of secondary amines[J]. CHEMICAL SCIENCE,2015,6(3):1873-1878.
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