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Asymmetric hydrogenation by RuCl2(R-Binap)(dmf)(n) encapsulated in silica-based nanoreactors
Peng, Juan1,2; Wang, Xuefeng1; Zhang, Xiaoming1,2; Bai, Shiyang1; Zhao, Yaopeng1; Li, Can1; Yang, Qihua1
刊名CATALYSIS SCIENCE & TECHNOLOGY
2015
DOI10.1039/c4cy00228h
5期:2页:666-672
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Physical
研究领域[WOS]Chemistry
关键词[WOS]CHIRAL CATALYSTS ; AROMATIC KETONES ; MAGNETITE NANOPARTICLES ; KINETIC RESOLUTION ; MESOPOROUS SILICA ; HYBRID SOLIDS ; ZEOLITE-Y ; BINAP ; RU ; COMPLEX
英文摘要The Noyori catalyst RuCl2(R-Binap)(dmf)(n) has been successfully encapsulated in C-FDU-12 by using the active chlorosilane Ph2Cl2Si as the silylating agent. P-31-NMR results show that there is no strong interaction between the molecular catalyst and the solid support, thus the encapsulated molecular catalyst could move freely in the nanoreactor during the catalytic process. The solid catalyst exhibits high activity and enantioselectivity for the asymmetric hydrogenation of a series of beta-keto esters due to the preserved intrinsic properties of RuCl2(R-Binap)(dmf)(n) encapsulated in the nanoreactor. The solid catalyst could be recycled by simple filtration and be reused at least four times.
语种英语
WOS记录号WOS:000348937900005
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文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/145956
专题中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
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GB/T 7714
Peng, Juan,Wang, Xuefeng,Zhang, Xiaoming,et al. Asymmetric hydrogenation by RuCl2(R-Binap)(dmf)(n) encapsulated in silica-based nanoreactors[J]. CATALYSIS SCIENCE & TECHNOLOGY,2015,5(2):666-672.
APA Peng, Juan.,Wang, Xuefeng.,Zhang, Xiaoming.,Bai, Shiyang.,Zhao, Yaopeng.,...&Yang, Qihua.(2015).Asymmetric hydrogenation by RuCl2(R-Binap)(dmf)(n) encapsulated in silica-based nanoreactors.CATALYSIS SCIENCE & TECHNOLOGY,5(2),666-672.
MLA Peng, Juan,et al."Asymmetric hydrogenation by RuCl2(R-Binap)(dmf)(n) encapsulated in silica-based nanoreactors".CATALYSIS SCIENCE & TECHNOLOGY 5.2(2015):666-672.
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